The WS2 solid lubricating films doped with Ag is prepared on 9Cr18 bearing steel by ion beam composite deposition technique. Then, the films is stored in an indoor environment (temperature 18 to 25℃, air relative humidity of 30% to 50%) for 8 years. The friction and wear, surface morphology, three-dimensional topography composition and chemical state of WS2-Ag solid lubricant films are detected by friction and wear testing machine (MS-T3000), FESEM,surface morphology meter and XPS before and after storage. Compared with unstore WS2-Ag solid lubrication film, The results show that the oxygen content increase, the oxidation Ag/W element, and the loss of S element are checked. The friction and wear morphology of the films has presented with lamellar or massive spalling. The wear resistance of WS2-Ag composite lubricating films is shortened 103 minutes than before storage, the films still has a good solid lubrication performance, because the Ag doped WS2, improve its deliquescence and antioxidant properties, which greatly prolongs life and performance of solid lubricating films.
QIU Weiwei, JIN Jie, LÜ Lili, MENG Xiangyu, MENG Hui
. Friction and Wear Properties of a Long-term Storage WS2-Ag Films Prepared by IBAD Technology[J]. Journal of Mechanical Engineering, 2018
, 54(6)
: 41
-47
.
DOI: 10.3901/JME.2018.06.041
[1] XU Shusheng,GAO Xiaoming,SUN Jiayi,et al. Comparative study of moisture corrosion to WS2 and WS2/Cu multilayer films[J]. Surface and Coatings Technology,2014,247(5):30-38.
[2] SCHARF T W,RAJENDRAN A,BANERJEE R,et al. Growth,structure and friction behavior of titanium doped tungsten disulphide (Ti-WS2) nanocomposite thin films[J]. Thin Solid Films,2009,517(19):5666-5675.
[3] BANERJEE T,CHATTOPADHYAY A K. Structural,mechanical and tribological properties of WS2-Ti composite coating with and without hard under layer of TiN[J]. Surface and Coatings Technology,2014,258(21):849-860.
[4] WAHL K J,DUNN D N,SINGER I L. Wear behavior of Pb-Mo-S solid lubricating coatings[J]. Wear,1999,230(2):175-183.
[5] HOLBERY J D,PFLUEGER E,SAVAN A,et al. Alloying MoS2 with Al and Au:Structure and tribological performance[J]. Surface and Coatings Technology,2003,169-170(3):716-720.
[6] XING Y,DENG J,ZHANG K,et al. Fabrication and dry cutting performance of Si3N4/TiC ceramic tools reinforced with the PVD WS/Zr soft-coatings[J]. Ceramics International,2015,41(8):10261-10271.
[7] NOSSA A,CAVALEIRO A. The influence of the addition of C and N on the wear behaviour of W-S-C/N coatings[J]. Surface and Coatings Technology,2001,142-144(3):984-991.
[8] NOSSA A,CAVALEIRO A. Mechanical behavior of W-S-N and W-S-C sputtered coatings deposited with a Ti inter-layer[J]. Surface and Coatings Technology,2003,163-164(2):552-560.
[9] EVARISTO M,NOSSA A,CAVALEIRO A. W-S-C sputtered films:Influence of the carbon alloying method on the mechanical properties[J].Surface and Coatings Technology,2005,200(1-4):1076-1079.
[10] ZABINSKI J S,DONLEY M S,MCDEVITT N T. Mechanistic study of the synergism between Sb2O3 and MoS2 lubricant systems using Raman spectroscopy[J]. Wear,1993,165(1):103-108.
[11] 王均安,于德洋,欧阳锦林. 二硫化钼溅射膜在潮湿空气中贮存润滑性能的退化与失效机理[J]. 摩擦学学报,1994,14(1):25-32. WANG Junan,YU Deyang,OUYANG Jinli. Study on the Mechanism of Lubrication degradation and failure of MoS2 sputtrerd films stored in the moist air[J]. Journal of Tribology,1994,14(1):25-32.
[12] 金杰,黄晓林,邱维维,等. IBAD制备WS2-Ag固体润滑膜在海南湿热环境的耐候性能[J]. 中国表面工程,2016,29(3):26-33. JIN Jie,HUANG Xiaolin,QIU Weiwei,et al. Failure behaviors of WS2-Ag composite solid lubrication films prepared by IBAD in hygrothermal environment in Hainan[J]. China Surface Engineering,2016,29(3):26-33.