特邀专栏:表面工程先进技术及其服役行为(上)

等离子射流与喷涂粒子微观交互作用研究现状

  • 王海斗 ,
  • 陈书赢 ,
  • 马国政 ,
  • 邢志国 ,
  • 何鹏飞 ,
  • 徐滨士
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  • 装甲兵工程学院装备再制造技术国防科技重点实验室 北京 100072
王海斗,男,1969年出生,博士,研究员,博士研究生导师。主要研究方向为再制造、表面工程、装备摩擦学。E-mail:wanghaidou@aliyun.com;陈书赢,男,1990年出生,博士研究生。主要研究方向为热喷涂、表面工程。E-mail:chenshuying90@163.com

收稿日期: 2017-05-15

  修回日期: 2017-09-21

  网络出版日期: 2017-12-20

基金资助

国家自然科学基金(51675531,51535011)和北京市自然科学基金(3172038)资助项目。

Research on the Micro Interaction of Plasma Jet and Spraying Particles: A Review

  • WANG Haidou ,
  • CHEN Shuying ,
  • MA Guozheng ,
  • XING Zhiguo ,
  • HE Pengfei ,
  • XU Binshi
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  • National Key Lab for Remanufacturing, Academy of Armored Forces Engineering, Beijing 100072

Received date: 2017-05-15

  Revised date: 2017-09-21

  Online published: 2017-12-20

摘要

从微观角度看,等离子喷涂层实质上是由大量喷涂粒子在等离子射流中经过一系列复杂的理化变换之后,撞击基体并迅速铺展凝固所形成的,因而熔滴撞击基体前的理化特性对涂层的组织结构、缺陷密度、力学性能等指标具有重要影响。通过对喷涂粒子基本特征参数、射流中的传热机理、传质机理与粒子加速行为四个方面的总结,详细综述等离子射流与喷涂粒子的交互作用过程。总体来说,温度、速度是粒子的基本特征参数,而采用一些综合温度与速度的复合参数(如熔融指数、雷诺数、韦伯数等)对熔滴的理化特性具有更好的表征效果;粒子的加热过程由表及里,受到热导率、比表面积、热容量、飞行路径及射流特性等多种因素影响,部分熔滴容易由于温度过高而发生汽化现象;处于熔融状态的粒子具有较高的活性,因而容易在射流中与气体介质发生反应,包括O2、N2、H2等,同时粉体内部也会发生一定的元素迁移或化学反应;粒子在射流中由于受到气流拖拽力、重力、热泳力及气压梯度力的综合作用而不断加速,同时会由于射流特性及熔化状态的差异而发生不同程度的破碎或细化现象。

本文引用格式

王海斗 , 陈书赢 , 马国政 , 邢志国 , 何鹏飞 , 徐滨士 . 等离子射流与喷涂粒子微观交互作用研究现状[J]. 机械工程学报, 2017 , 53(24) : 1 -11 . DOI: 10.3901/JME.2017.24.001

Abstract

Microscopically, plasma sprayed coating is essentially fabricated by a stream of particles which experience a series of complicated physicochemical transformations in plasma jet and undergo rapid spreading and solidification after impacting the substrate. Therefore, the deposition quality of the droplet before impinging on the substrate has an important influence on the microstructure, defect and mechanical properties of the coating. The detail process of the interaction between plasma jet and particles is introduced in four aspects, namely, the basic parameters, the mechanism of the heat, mass and momentum transfer. The results indicate that the temperature and the velocity are the basic characteristic parameters of the particles, while the synthetic parameters of the temperature and velocity are proved to be more suitable to characterize the deposition quality of the droplets; the particles are heated from surface to interior and some of the droplets are prone to vaporize due to high melting status, which are effected by thermal coefficient, specific surface area, heat capacity, injection path, jet characteristics and so on; the molten droplets is easily to react with the atmosphere, i.e. O2, N2 and H2, due to high chemical activity, which can lead to the element migration and chemical reaction in the powder; the particles injected into the plasma jet are accelerated by the drag force, gravity, thermophoretic force and pressure gradient force, which can resulting in different degrees of fragmentation or refinement of the particles owing to the characteristics of the plasma jet and the molten state of the droplets.

参考文献

[1] ZHOU Liang,LUO Fa,ZHOU Wancheng,et al. Influence of FeCrAl Content on microstructure and bonding strength of plasma-sprayed FeCrAl/Al2O3 coatings[J]. Journal of Thermal Spray Technology,2016,25(3):509-517.
[2] BITZER M,RAUHUT N,MAUER G,et al. Cavitation-resistant NiTi coatings produced by low-pressure plasma spraying (LPPS)[J]. Wear,2015,328-329:369-377.
[3] WANG L,HABIBI M H,ELDRIDGE J I,et al. Infrared radiative properties of plasma-sprayed BaZrO3 coatings[J]. Journal of the European Ceramic Society,2014,34(15):3941-3949.
[4] FAUCHAIS P L,HEBERLEIN J V R,BOULOS M I. Thermal Spray Fundamentals[M]. New York:Springer,2014.
[5] 李国禄,李楠楠,王海斗,等. 不同喷涂工艺制备的Al2O3-13%TiO2涂层表面自由能与冲蚀磨损性能研究[J]. 机械工程学报,2016,52(10):59-66. LI Guolu,LI Nannan,WANG Haidou,et al. Research on surface free energy and erosion wear property of A12O3-13% TiO2 coatings prepared by different spraying processes[J]. Journal of Mechanical Engineering,2016,52(10):59-66.
[6] 陈书赢,王海斗,徐滨士,等. 热喷涂层滚动接触疲劳寿命演变规律研究进展[J]. 机械工程学报,2014,50(8):23-33. CHEN Shuying,WANG Haidou,XU Binshi,et al. Law of rolling contact fatigue life of thermal spray coatings:A review[J]. Journal of Mechanical Engineering,2014,50(8):23-33.
[7] 王海斗,朱丽娜,徐滨士. 纳米压痕法测量等离子喷涂铁基涂层表面的残余应力[J]. 机械工程学报,2013,49(7):1-4. WANG Haidou,ZHU Lina,XU Binshi. Measurement of residual stress of plasma sprayed Fe-based coating by nanoindentation[J]. Journal of Mechanical Engineering,2013,49(7):1-4.
[8] LEVINGSTONE T J,ARDHAOUI M,BENYOUNIS K,et al. Plasma sprayed hydroxyapatite coatings:Understanding process relationships using design of experiment analysis[J]. Surface & Coatings Technology,2015,283:29-36.
[9] YUSOFF N H N,GHAZALI M J,ISA M C,et al. Optimization of plasma spray parameters on the mechanical properties of agglomerated Al2O3-13%TiO2,coated mild steel[J]. Materials & Design,2012,39(3):504-508.
[10] HEIMANN R B. Plasma-spray coating:principles and applications[M]. New Jersey:John Wiley & Sons,2008.
[11] 许中林,董天顺,康嘉杰,等. 基于均匀设计的NiCr-Cr3C2超声速等离子喷涂工艺参数优化[J]. 机械工程学报,2014,50(18):43-49. XU Zhonglin,DONG Tianshun,KANG Jiajie,et al. Parameters optimizing of NiCr-Cr3C2 coating deposited by supersonic plasma spraying based on uniform design[J]. Journal of Mechanical Engineering,2014,50(18):43-49.
[12] FAUCHAIS P,VARDELLE A. Heat,mass and momentum transfer in coating formation by plasma spraying[J]. International Journal of Thermal Sciences,2000,39(9-11):852-870.
[13] LIU T,ANSAR A,ARNOLD J. A Study of the Influence of the Surrounding Gas on the Plasma jet and coating quality during plasma spraying[J]. Plasma Chemistry & Plasma Processing,2017:1-24.
[14] CIZEK J,KHOR K A. Role of in-flight temperature and velocity of powder particles on plasma sprayed hydroxyapatite coating characteristics[J]. Surface & Coatings Technology,2012,206:2181-2191.
[15] KIRSTEN B,NILS K,THOMAS W,et al. Particle in-flight and coating properties of Fe-based feedstock materials sprayed with modern thermal spray systems[J]. Journal of Thermal Spray Technology,2012,22:363-370.
[16] FANG J,XU W,ZHAO Z,et al. In-flight behaviors of ZrO2 particle in plasma spraying[J]. Surface & Coatings Technology,2007,201:5671-5675.
[17] ZHAO Lidong,KLAUS S,ARNE F,et al. Study on atmospheric plasma spraying of Al2O3 using on-line particle monitoring[J]. Surface and Coatings Technology,2003,168:186-190.
[18] WANG Y,HUA J,LIU Z,et al. Melting index characterization and thermal conductivity model of plasma sprayed YSZ coatings[J]. Journal of the European Ceramic Society,2012,32(14):3701-3707.
[19] LI Li,ANIRUDHA V,SANJAY S,et al. Particle characterization and splat formation of plasma sprayed zirconia[J]. Journal of Thermal Spray Technology,2006,15(1):97-105.
[20] LIU Kun,TAN Jianjiang,BAI Yu,et al. Particle in-flight behavior and its influence on the microstructure and mechanical property of plasma sprayed La2Ce2O7 thermal barrier coatings[J]. Materials Science & Engineering A,2015,625:177-185.
[21] LI H,COSTIL S,LIAO H L,et al. Effects of surface conditions on the flattening behavior of plasma sprayed Cu splats[J]. Surface & Coatings Technology,2006,200:5435-5446.
[22] DHIMAN R,CHANDRA S. Freezing-induced splashing during impact of molten metal droplets with high Weber numbers[J]. International Journal of Heat & Mass Transfer,2005,48(25):5625-5638.
[23] 陈丹,王玉,白宇,等. 等离子喷涂中雷诺数对熔滴扁平化行为的影响[J]. 无机材料学报,2015,30(1):65-70. CHEN Dan,WANG Yu,BAI Yu,et al. Effect of Reynolds number of molten particle on splat formation in plasma spraying[J]. Journal of Inorganic Materials,2015,30(1):65-70.
[24] FAUCHAIS P,VARDELLE A,VARDELLE M,et al. Knowledge concerning splat formation:An invited review[J]. Journal of Thermal Spray Technology,2004,13(3):337-360.
[25] SYED A A,DENOIRJEAN A,HANNOYER B,et al. Influence of substrate surface conditions on the plasma sprayed ceramic and metallic particles flattening[J]. Surface & Coatings Technology,2005,200:2317-2331.
[26] 谭超,魏正英,魏培,等. 内送粉超音速等离子喷涂颗粒飞行状态分析[J]. 西安交通大学学报,2014,48(6):91-97. TAN Chao,WEI Zhengying,WEI Pei,et al. In-flight particle behavior in internal powder injection supersonic plasma spray[J]. Journal of Xi'an Jiaotong University,2014,48(6):91-97.
[27] FAUCHAIS P. Understanding plasma spraying[J]. Journal of Physics D Applied Physics,2004,37(9):86-108.
[28] SELVAN B,RAMACHANDRAN K,SREEKUMAR K P,et al. Numerical and experimental studies on DC plasma spray torch[J]. Vacuum,2010,84:444-452.
[29] SHSHIEN,YAMADA M,FUKUMOTO M,et al. Reactive plasma-sprayed aluminum nitride-Based coating thermal conductivity[J]. Journal of Thermal Spray Technology,2015,24(8):1385-1398.
[30] SOFIANE G,GHASLAIN M,CHRISTIAN C. Velocity and temperature distributions of alumina-titania in-flight particles in the atmospheric plasma spray process[J]. Surface & Coatings Technology,2005,192:70-76.
[31] SHANMUGAVELAYUTHAM G,SELVARAJAN V,THIYAGARAJAN T K,et al. In-flight particle behaviour and its effect on co-spraying of alumina-titania[J]. Current Applied Physics,2006,6:41-47.
[32] FAN Qunbo,WANG Lu,WANG Fuchi. Modeling influence of basic operation parameters on plasma jet[J]. Journal of Materials Processing Technology,2008,198:207-212.
[33] WANG P,YU S,NG H. Particle velocities,sizes and flux distribution in plasma spray with two powder injection ports[J]. Materials Science and Engineering A,2004,383:122-136.
[34] XIONG Hongbing,ZHENG Lili,SANJAY S,et al. Three-dimensional simulation of plasma spray:effects of carrier gas flow and particle injection on plasma jet and entrained particle behavior[J]. International Journal of Heat and Mass Transfer,2004,47:5189-5200.
[35] ZHOU L,DONG Y,WANG Z,et al. Influence of Cr content and initial Cr particle size on the dielectric properties of plasma-sprayed Cr/Al2O3 coatings[J]. Surface & Coatings Technology,2017,313:374-380.
[36] ZHOU Liang,LUO Fa,ZHOU Wangcheng,et al. Influence of FeCrAl content on microstructure and bonding strength of plasma-sprayed FeCrAl/Al2O3 coatings[J]. Journal of Thermal Spray Technology,2016,25(3):509-517.
[37] SUDHAKAR C J,BANDYOPADHYAY P P. Plasma sprayed carbon nanotube reinforced splats and coatings[J]. Journal of the European Ceramic Society,2017,37:2235-2244.
[38] ANUP K K,DEBRUPA L,ARVIND A. Carbon nanotubes improve the adhesion strength of a ceramic splat to the steel substrate[J]. Carbon,2011,49:4340-4347.
[39] BAI Y,TANG J J,QU Y M,et al. Influence of original powders on the microstructure and properties of thermal barrier coatings deposited by supersonic atmospheric plasma spraying,Part I:Microstructure[J]. Ceramics International,2013,39(5):5113-5124.
[40] YIN Zhijian,TAO Shunyan,ZHOU Xiaming,et al. Particle in-flight behavior and its influence on the microstructure and mechanical properties of plasma-sprayed Al2O3 coatings[J]. Journal of the European Ceramic Society,2008,28:1143-1148.
[41] YUGESWARAN S,KOBAYASHI A,SELVAN B,et al. In-flight behavior of lanthanum zirconate (La2Zr2O7) particles in gas tunnel type plasma jet and its coating properties[J]. Vacuum,2013,88:139-143.
[42] ZENG Shangwu,ZHAO Aimin,JIANG Haitao. Oxidation of conventional and nanostructured 8 wt.% yttria-stabilized zirconia coating surface coatings on γ-TiAl[J]. Applied Surface Science,2015,332:362-367.
[43] YAN Q,GAMBINO R J,SAMPATH S,et al. Effects of zinc loss on the magnetic properties of plasma-sprayed MnZn ferrites[J]. Acta Materialia,2004,52(11):3347-3353.
[44] SHINODA K,LIANG S S,SAMPATH S,et al. Processing effects on in-flight particle state and functional coating properties of plasma-sprayed manganese zinc ferrite[J]. Materials Science and Engineering B,2011,176:22-31.
[45] ROBOTTI M,DOSTA S,GARDON M,et al. Enhancing the performance of common electrode materials by means of atmospheric plasma spray coatings[J]. Journal of Energy Storage,2016,5:127-133.
[46] TIAN Jiajia,YAO Shuwei,LUO Xiaotao,et al. An effective approach for creating metallurgical self-bonding in plasma-spraying of NiCr-Mo coating by designing shell-core-structured powders[J]. Acta Materialia,2016,110:19-30.
[47] 张林伟,魏琪,李辉,等. 热喷涂粒子氧化机理分析及其保护方法概述[J]. 材料工程,2009(6):78-82. ZHANG Linwei,WEI Qi,LI Hui,et al. Oxidization behavior of thermally sprayed particles and the relevant protective techniques[J]. Journal of Materials Engineering,2009(6):78-82.
[48] QI Wei,YIN Zhiyong,LI Hui. Oxidation control in plasma spraying NiCrCoAlY coating[J]. Applied Surface Science,2012,258:5094-5099.
[49] SYED A A,DENOIRJEAN A,FAUCHAIS P,et al. On the oxidation of stainless steel particles in the plasma jet[J]. Surface & Coatings Technology,2006,200(14-15):4368-4382.
[50] WAN Y P,FINCKE J R,JIANG X Y,et al. Modeling of oxidation of molybdenum particles during plasma spray deposition[J]. Metallurgical and Materials Transactions B,2001,32(3):475-481.
[51] PLANCHE M P,LIAO H,CODDET C. Oxidation control in atmospheric plasma spraying coating[J]. Surface & Coatings Technology,2007,202(1):69-76.
[52] CIZEK J,KHOR K A,DLOUHY I. In-flight temperature and velocity of powder particles of plasma-sprayed TiO2[J]. Journal of Thermal Spray Technology,2013,22(8):1320-1327.
[53] MATTHEWS S. Development of high carbide dissolution/low carbon loss Cr3C2-NiCr coatings by shrouded plasma spraying[J]. Surface & Coatings Technology,2014,258:886-900.
[54] MATTHEWS S. Carbide dissolution/carbon Loss as a function of spray distance in unshrouded/shrouded plasma sprayed Cr3C2-NiCr coatings[J]. Journal of Thermal Spray Technology,2015,24(3):1-18.
[55] SHAHIEN M,YAMADA M,FUKUMOTO M. Challenges upon reactive plasma spray nitriding:Al powders and fabrication of AlN coatings as a case study[J]. Journal of Thermal Spray Technology,2016,25(5):1-23.
[56] SHAHIEN M,YAMADA M,YASUI T,et al. N2 and H2 plasma gasses' effects in reactive plasma spraying of Al2O3,powder[J]. Surface & Coatings Technology,2013,216:308-317.
[57] SHAHIEN M,YAMADA M,FUKUMOTO M,et al. Reactive plasma-sprayed aluminum nitride-based coating thermal conductivity[J]. Journal of Thermal Spray Technology,2015,24(8):1385-1398.
[58] 夏铭,王泽华,周泽华,等. 反应等离子喷涂TiN复相涂层的组织与性能研究[J]. 粉末冶金工业,2016,26(3):38-43. XIA Ming,WANG Zehua,ZHOU Zehua,et al. Research on microstructure and properties of reactive plasma spraying TiN composite coatings[J]. Powder Metallurgy Industry,2016,26(3):38-43.
[59] YAO Yihong,WANG Zehua,ZHOU Zehua,et al. Study on reactive atmospheric plasma-sprayed in situ titanium compound composite coating[J]. Journal of Thermal Spray Technology,2013,22(4):509-517.
[60] GARDON M,GUILEMANY J M. Milestones in functional titanium dioxide thermal spray coatings:a review[J]. Journal of Thermal Spray Technology,2014,23(4):577-595.
[61] GARDON M,DOSTA S,GUILEMANY J M,et al. Improved,high conductivity titanium sub-oxide coated electrodes obtained by atmospheric plasma spray[J]. Journal of Power Sources,2013,238(238):430-434.
[62] LEE H,SU J H,SESHADRI R C,et al. Thermoelectric properties of in-situ plasma spray synthesized sub-stoichiometry TiO2-x[J]. Scientific Reports,2016,6:1-11.
[63] YUAN Jianhui,ZHAN Qing,HUANG Jing,et al. Decarburization mechanisms of WC-Co during thermal spraying:Insights from controlled carbon loss and microstructure characterization[J]. Materials Chemistry & Physics,2013,142(1):165-171.
[64] WANF Haidou,MA Jianlong,LI Guolong,et al. The dependency of microstructure and mechanical properties of nanostructured alumina-titania coatings on critical plasma spraying parameter[J]. Applied Surface Science,2014,314(10):468-475.
[65] CIZEK J,DLOUHY I,SISKA F,et al. Modification of plasma-sprayed TiO2 coatings characteristics via controlling the in-flight temperature and velocity of the powder particles[J]. Journal of Thermal Spray Technology,2014,23(8):1339-1349.
[66] XU J,ZOU B,TAOS,et al. Fabrication and properties of Al2O3-TiB2-TiC/Al metal matrix composite coatings by atmospheric plasma spraying of SHS powders[J]. Journal of Alloys & Compounds,2016,672:251-259.
[67] ZOU Binglin,TAO Shunyan,HUANG Wenzhi,et al. Synthesis and characterization of in situ TiC-TiB2 composite coatings by reactive plasma spraying on a magnesium alloy[J]. Applied Surface Science,2013,264:879-885.
[68] WANG Lei,YAN Dianran,YANG Yong,et al. Structure and properties of nanostructured ceramic matrix composite coatings prepared in-situ by reactive plasma spraying micro-sized Al-Fe2O3-Cr2O3 powders[J]. Ceramics International,2014,40:6481-6486.
[69] HE Jining,ZHANG Fanyong,MI Pengbo,et al. Microstructure and wear behavior of nano C-rich TiCN coatings fabricated by reactive plasma spraying with Ti-graphite powders[J]. Surface & Coatings Technology,2016,305:215-222.
[70] MI P,HE J,QIN Y,et al. Nanostructure reactive plasma sprayed TiCN coating[J]. Surface & Coatings Technology,2016,309-314.
[71] ZHAN Qing,YU Ligen,YE Fuxing,et al. Quantitative evaluation of the decarburization and microstructure evolution of WC-Co during plasma spraying[J]. Surface & Coatings Technology, 2012,206:4068-4074.
[72] NIRANATLUMPONG P,SUKONKHET C,NINON K. Loss of Y from NiCrAlY powder during air plasma spraying[J]. Surface & Coatings Technology,2015,280:277-281.
[73] PEI W,WEI Z,ZHAO G,et al. The analysis of melting and refining process for in-flight particles in supersonic plasma spraying[J]. Computational Materials Science,2015,103(9):8-19.
[74] BAI Y,ZHAO L,QU Y,et al. Particle in-flight behavior and its influence on the microstructure and properties of supersonic-atmospheric-plasma-sprayed nanostructured thermal barrier coatings[J]. Journal of Alloys and Compounds,2015,644:873-882.
[75] BAI Y,ZHAO L,WANG Y,et al. Fragmentation of in-flight particles and its influence on the microstructure and mechanical property of YSZ coating deposited by supersonic atmospheric plasma spraying[J]. Journal of Alloys and Compounds,2015,632:794-799.
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