2022年, 第19卷, 第2期 
刊出日期:2022-03-28
  

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    Research & Development
  • Tan Wan, Gang-qiang Liang, Zhao-ming Wang, Can-xu Zhou, Yuan Liu
    《中国铸造》英文版. 2022, 19(2): 89-98. https://doi.org/10.1007/s41230-022-1159-2
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    The infiltration casting fabrication process based on spherical CaCl2 space-holders and the compressive behavior including the mechanical performance and energy absorption capacity of open-cell aluminum foams were investigated. Open-cell aluminum foams with different porosities in the range of 63.1% to 87.3% can be fabricated by adjusting compression ratios of CaCl2 preforms prepared by precision hot-pressing. The compression tests show that a strain-hardening phenomenon always occurs especially for open-cell aluminum foam with low porosity, resulting in the inclining stress-strain curve in the plateau region. The energy absorption capacity of open-cell aluminum foam decreases with increasing porosity when compared at the same strain. However, when compared at a given stress, each foam can absorb the maximal energy among the five foams in a special stress range. Additionally, open-cell aluminum foam possesses the maximum energy absorption efficiency at its optimum operating stress. At this stress condition, the foam can absorb the highest energy compared with other foams at the same stress point. The optimum operating stress and the corresponding maximal energy absorption decrease with increasing the porosity. The optimum operating stress for energy absorption can also be determined similarly when taking into consideration of the lightweight extent of foams.
  • Yong-zhi Hao, Hai-dong Zhao, Xu Shen, Xue-ling Wang, Hui-ting Zheng
    《中国铸造》英文版. 2022, 19(2): 99-108. https://doi.org/10.1007/s41230-022-1176-1
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    Al-Si-Mg alloys are the most commonly used material in high vacuum die-casting (HVDC), in which the morphology and distribution of α-Al grains have important effect on mechanical properties. A multi-component quantitative cellular automaton (CA) model was developed to simulate the microstructure and microsegregation of HVDC Al-Si-Mg alloys with different Si contents (7% and 10%) and cooling rates during solidification. The grain number and average grain size with electron backscatter diffraction (EBSD) analysis were used to verify the simulation. The relationship between grain size and nucleation order as well as nuclei density was investigated and discussed. It is found that the growth of grains will be restrained in the location with higher nuclei density. The influence of composition and cooling rate on the solute transport reveals that for AlSi7Mg0.3 alloy the concentration of solute Mg in liquid is higher at the beginning of eutectic solidification. The comparison between simulation and experiment results shows that externally solidified crystals (ESCs) have a significant effect for samples with high cooling rate and narrow solidification interval.
  • Mang Xu, Xiao-qi Geng, Xiang-long Zhang, Guo-huai Liu, Ye Wang, Zhao-dong Wang, Jing-jie Guo
    《中国铸造》英文版. 2022, 19(2): 109-116. https://doi.org/10.1007/s41230-022-1033-2
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    Directionally solidified single crystal superalloy test bars were prepared by the spiral grain selection method. The microstructural evolution and orientation characteristics of the starter block and spiral part were studied, and the influence of the competitive growth of crystals on the microstructural characteristics was analyzed. The results show that the divergent grain groups, with small size and randomly oriented grains, appear at the bottom of the start block due to the chilling effect, which is an important area for competitive growth. As the height of the starter block increases, the primary dendrite spacing increases, and the grain density decreases; furthermore, the proportion of grains with an orientation deflection angle less than 10° gradually increases. The <001> texture gradually becomes stronger as the height of the starter block increases, which indicates that the competitive growth of crystals gradually weakens. At the initial stage of the crystal selection in the spiral part, the obstacle of adjacent grains and spiral passage is the main working mechanism. The grains located at the inner side of the front edge of the spiral passage have the growth advantage. The single crystal screening process is achieved at about two-thirds of the spiral height, and the single crystal with the orientation deviation angle of 6.7° from the casting axis is prepared.
  • Zong-xu Zhang, Ti-jun Chen, Kun Liu, Han Xue, Jia-chen Qi, Guang-li Bi, Ying Ma
    《中国铸造》英文版. 2022, 19(2): 117-130. https://doi.org/10.1007/s41230-022-1134-y
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    Subjecting a normal mechanical vibration to a cooling slope plate, is a proposed method for preparing semisolid nondendritic slurry, named shear-vibration coupling sub-rapid solidification (SCS). Taking Al-8Si alloy as model material, the temperature field and distribution field of solid or liquid phase during SCS were simulated using COMSOL Multiphysics software to primarily choose the optimal processing parameters. Subsequently, the slurries were prepared with the parameters selected according to the simulation results and the microstructures of the slurries were experimentally investigated. Results indicate that the simulation results could provide a basis for roughly choosing the processing parameters, although the calculated solid fractions are always higher than the experimental ones. The processing parameters affect the primary grain size, shape factor and solid fraction mainly through altering the contact duration of melt on the plate, and thus affecting the cooling effect on the melt, nucleation rate, and grain dissociation and proliferation. Experiments with optimized processing parameters show that the primary grains in the slurry have an average size of about 32 μm and shape factor of 1.38, and are quite uniform, even at the highest pouring rate of 2.81 kg·s-1, the size and shape factor are about 46 μm and 1.7, respectively, which implies that the proposed SCS is a promising technology for efficient fabrication of high-quality Al slurry available for engineering applications.
  • He Qin, Guang-yu Yang, Xun-wei Zheng, Shi-feng Luo, Tong Bai, Wan-qi Jie
    《中国铸造》英文版. 2022, 19(2): 131-139. https://doi.org/10.1007/s41230-022-1117-z
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    The hot-tearing susceptibility (HTS) of Mg-6Zn-xGd (x=0.5, 1, 2, 3, 4, 6) alloys was evaluated using a constrained rod casting (CRC) method. The results show that the HTS curve follows a typical “Λ” shape with the increase of Gd content. The Mg-6Zn-2Gd alloy has the highest while Mg-6Zn-6Gd alloy has the lowest HTS value. The hot-tearing behavior characteristics of Mg-6Zn-xGd alloys were further studied through a multifunctional hot-tearing test device. According to the dendrite contact point inferred from the stress curve, the Clyne-Davies criterion was modified and found to be accurate in predicting the HTS of Mg-6Zn-xGd alloys. Microstructure observation reveals that the grain size and the volume of eutectic liquid are the two key factors affecting HTS of Mg-6Zn-xGd alloys. The large grain with columnar structure can easily promote initiation and propagation of hot-tearing due to the poor feeding and coordinating deformation capability, which have a harmful effect on HTS. A higher volume fraction of eutectic phase can refill the cracking and provide continuous feeding channels by dendrite bridge and thicker liquid film, thus increase the hot-tearing resistance.
  • Xue-wen Qian, Peng Wan, Ya-jun Yin, Yu-yang Qi, Xiao-yuan Ji, Xu Shen, Yuan-cai Li, Jian-xin Zhou
    《中国铸造》英文版. 2022, 19(2): 140-148. https://doi.org/10.1007/s41230-022-1031-4
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    No-bake resin-bonded sand is commonly used in casting production. However, its air pollution is relatively serious, especially in the molding and pouring process. For this reason, it is necessary to study the gas evolution characteristics of no-bake resin-bonded sand from room temperature to high temperatures, and not only the amount of gaseous products, but also the composition of the gaseous products. No-bake furan resin-bonded sand (#1), phenolic urethane no-bake resin-bonded sand (#2), and alkaline phenolic no-bake resin-bonded sand (#3) are the three most common no-bake resin-bonded sands in casting. The gas evolution volume and rate of these three no-bake resin-bonded sands were studied. Thermogravimetry-mass spectrometer (TG-MS), headspace-gas chromatography/mass spectrometer (HS-GC/MS), and pyrolysis-gas chromatography/mass spectrometer (PY-GC/MS) were used to measure the composition of the gaseous products emitted from binders at room temperature and high temperatures. The differences between formaldehyde, heterocyclic aromatic compounds (HAC), monocyclic aromatic hydrocarbons (MAH), and polycyclic aromatic hydrocarbons (PAHs) gaseous products from the three types of no-bake resin-bonded sands during the molding and casting process were compared. From the perspective of environmental protection, alkaline phenolic no-bake resin-bonded sand and no-bake furan resin-bonded sand are better than phenolic urethane no-bake resin-bonded sand.
  • Ying Wang, Pan-yu Chen, Yu-hui Lin, Mei Zhao, Cheng-dong Li
    《中国铸造》英文版. 2022, 19(2): 149-157. https://doi.org/10.1007/s41230-022-9003-2
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    To obtain high-performance Al-Si-based cast alloys, refinement and modification of Si phases are required. An Al-12Si/ZnS powder inoculant was designed and fabricated using a chemical bath deposition method. The efficiency of the inoculant for modifying the eutectic Si phase in as-cast Al-12Si alloy was studied. Results show that Al-12Si/ZnS powder can significantly refine the eutectic Si in Al-Si cast alloys. The best refinement effect for eutectic Si is achieved with 17.5wt.% Al-12Si/ZnS powder. Coarse long needle-shaped eutectic Si with a length of 18 μm was modified into approximately spherical shape with a diameter of 6.53 μm, which is evenly distributed throughout the alloy. The E2EM model calculation indicates that the inter-plane misfit (Fp) and inter-atomic spacing misfit (Fr) between ZnS and Si are all less than 0.5%, which confirms that ZnS is a potential nucleation site for Si phase. The hardness, tensile strength, and elongation of Al-12Si alloys modified with 17.5% Al-12Si/ZnS powder increase 6.30%, 16.18% and 55.45%, respectively, compared to the unmodified Al-12Si alloy. The fracture behavior of the alloy with 17.5wt.% Al-12Si/ZnS powder is dominated by transgranular fracture supplemented by intergranular fracture.
  • Tian-yu Liu, Zhi-hao Zhu, Shuang Zhang, Xiao-hua Min, Chuang Dong
    《中国铸造》英文版. 2022, 19(2): 158-168. https://doi.org/10.1007/s41230-022-1066-6
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    A novel Ti-6.38Al-3.87V-2.43Mo alloy was designed with a cluster formula of 12[Al-Ti12] (V0.75Mo0.25Ti2)+4[Al-Ti12](Al3) by replacing Ti with Mo/V on the basis of the Ti-Al congruent alloy. The effects of laser power and scanning speed on the molten pool size, surface roughness, relative density, microstructure, and micro-hardness of single-track and bulk Ti-6.38Al-3.87V-2.43Mo samples prepared via laser additive manufacturing (LAM) were investigated. The results show that processing parameters significantly affect the formability, microstructure, and micro-hardness of the alloy. With decreasing laser power from 1,900 W to 1,000 W, the relative density is decreased from 99.86% to 90.91% due to the increase of lack-of-fusion; however, with increasing scanning speed, the relative density does not change significantly, but exceeds 99%. In particular, Ti-6.38Al-3.87V-2.43Mo samples of single-track and bulk exhibit a good formability under an input laser power of 1,900 W and a scanning speed of 8 mm·s-1, and display the lowest surface roughness (Ra=13.33 μm) and the highest relative density (99.86%). Besides, the microstructure of LAM Ti-6.38Al-3.87V-2.43Mo alloy coarsens with increasing laser power or decreasing scanning speed due to the greater input energy reducing the cooling rate. The coarsening of the microstructure decreases the microhardness of the alloy.
  • Ming-chen Ma, Chao-qing Luo, Si-min Chen, Hong-qun Tang, Shan-shan Hu, Yu-mei Zhou, Jian-lin Liang
    《中国铸造》英文版. 2022, 19(2): 169-176. https://doi.org/10.1007/s41230-022-1034-1
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    Boron and carbon contents are the main factors influencing the properties of high-boron steel. In this study, experimental samples with different boron-to-carbon ratios (%B/%C) were prepared. The microstructures of the different samples were observed, and their hardness, bending strength, and impact toughness were investigated. Results show that the main microstructures in the investigated high-boron steel samples are the eutectic Fe2B structure with a fishbone shape and the ternary peritectic Fe3(C, B) structure with a chrysanthemum shape. When the boron content is 2.5wt.% and the carbon content is 0.43wt.% (i.e., %B/%C=5.82), the overall mechanical properties of the alloy are the best. The alloy’s hardness, bending strength and impact toughness reach their maximums, which are 67.3 HRC, 1,267.36 MPa and 6.19 J·cm-2, respectively. The optimized alloy is compared with conventional materials exhibiting excellent wear resistance (namely, high-manganese steel and high-chromium cast iron) through two-body and three-body abrasion tests. The wear resistance of this high-boron steelinvestigated in this work is found to be superior to those of the more common materials.
  • Yu-xuan Zhang, Jun-sheng Wang, Dong-xu Chen, Bing Wang, Chi Zhang, Zheng-an Wang
    《中国铸造》英文版. 2022, 19(2): 177-190. https://doi.org/10.1007/s41230-022-1183-2
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    During the direct chill (DC) casting process, primary cooling from the mold and bottom block, and secondary cooling from the waterjets produce a concave solid shell. The depth of this liquid pocket and mushy zone not only depends on the solidification range of the alloy but also the boundary conditions such as cooling rates. Al-Li alloys solidify in a long solidification range increasing the susceptibility of porosity nucleation in the semi-solid region. In this study, the effects of cooling rate on the porosity formation were quantified for the large ingot casting using X-ray computed tomography (XCT). By characterizing pore size distributions at four different cooling conditions, the correlation between the mechanical properties at both room and high temperatures and the microstructure features was identified. The constitutive equations were constructed. It is found that increasing the cooling rate reduces the grain size, increases the number density of micropores, and minimizes the number of large pores, thereby improving the mechanical performance. Therefore, long mushy zones and deep liquid pockets in Al-Li alloys can be effectively controlled by controlling the boundary conditions of the DC casting solidification process, thereby obtaining castings with excellent mechanical properties.