2021年, 第18卷, 第5期 
刊出日期:2021-09-28
  

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    Research & Development
  • Zhe-feng Liu, Kai Miao, Wei-bo Lian, Zhong-liang Lu, Chen Yi, Di-chen Li
    《中国铸造》英文版. 2021, 18(5): 433-441. https://doi.org/10.1007/s41230-021-1073-z
    摘要 ( ) PDF全文 ( )   可视化   收藏
    Stray grains, the most serious casting defect, mainly occur in the platform because of the abrupt transition of the cross-section in the directional solidification of superalloy single-crystal blades. A new mould baffle technology based on 3D printing and gelcasting is proposed herein to reduce the formation of stray grains in the platform. The influence of the proposed mould baffle technology on the temperature field in the platform during solidification was investigated by simulation and experiment. The numerical simulation results indicate that the proposed mould baffle technology can effectively hinder the radiation and heat dissipation at the platform extremities, and therefore, reduce undercooling in the platform and the formation of stray grains during directional solidification. Casting trials of a hollow turbine blade were conducted using CMSX-4 superalloy. The trial results demonstrate the potential of the proposed approach for manufacturing single-crystal superalloy blades.
  • Zhen-yu Yang, Chen-guang Liu, Song-song Hu, Su-jie Zheng, Yu-shi Luo, Shen-long Dai
    《中国铸造》英文版. 2021, 18(5): 442-449. https://doi.org/10.1007/s41230-021-1053-3
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    Stray grains are the most severe of the solidification defects that occur in the industrial single-crystal blade preparation process. In this study, a single-crystal dummy blade cluster with different crystal orientations controlled by the seeding method was prepared, and the influence of the position of the circular platform (relative to the sample and furnace body) on stray grain nucleation was investigated. Results show that the microstructure of the circular platforms could be divided into the center, expansion, and stray grain regions. The inside of the circular platform facing the center of the cluster is more prone to stray grain formation than the outside of the circular platform facing the furnace body. With an increase in the distance between the circular platform and the bottom of the dummy blade cluster, the stray grain region expands, whereas the expansion region narrows. The stray grain is slightly aggravated with increase of the misorientation. Finally, the mechanism underlying the influence of platform position on the formation of stray grains in single-crystal dummy blade clusters is discussed based on the temperature evolution during directional solidification.
  • Cong-ran Fu, Wei Zhang, Qing-chun Xiang, Ying-dong Qu, Ying-lei Ren, Bo Yu, Ke-qiang Qiu
    《中国铸造》英文版. 2021, 18(5): 450-456. https://doi.org/10.1007/s41230-021-1061-3
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    Fe-based bulk metallic glasses (BMGs) with high boron content have potential application as a coating material used in the framework for storing spent nuclear fuels to support their safe long-term disposal. The high glass forming ability (GFA) and large supercooled liquid region are therefore required for such Fe-based BMGs in either the glassy powder fabrication or the subsequent coating spraying. In order to meet these requirements, the influence of Nb content on the GFA of Fe57Cr10Zr8B18Mo7-xNbx (x=1–5, at.%) alloys was investigated, as Nb has positive roles in GFA and thermal stability of BMGs. The results indicate that a fully amorphous phase in the as-cast samples with 3 mm in diameter is obtained for both the Fe57Cr10Zr8B18Mo5Nb2 and Fe57Cr10Zr8B18Mo4Nb3 alloys. The corresponding supercooled liquid regions of the two BMGs are 78 K and 71 K, respectively. The mechanism for improving their GFA was analyzed based on the principle of metal solidification, the parameters for glass formation and thermal properties of the alloys. The compression strength and Vicker’s hardness of the two BMGs are 1,950 MPa and 1,310 HV, 2,062 MPa and 1,180 HV, respectively. The developed BMGs with high B content, good GFA, and very high hardness can be used as coating materials to the framework for spent nuclear fuels.
  • Zhi-ping Pan, Jian-zheng Guo, Shuang-ming Li, Xu-guang Li
    《中国铸造》英文版. 2021, 18(5): 457-462. https://doi.org/10.1007/s41230-021-1024-8
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    During sintering of the silica-based ceramic core of turbine blades, a phenomenon called “nonuniform sintering” occurs that negatively affects the thermal and mechanical properties of the core. Standard samples of silica-based core were prepared by an injection molding method and sintered with alumina backfilling powder with different sodium contents. The effect of sodium content on the nonuniform sintering of silica-based cores and the thermal and mechanical properties was evaluated. Results show that the sintering level and the content of α-cristobalite in the surface layer are significantly higher than that of the sample interior. A considerable number of microcracks are found in the surface layer due to the β to α-phase transition of cristobalite. As the sodium content in the alumina powder decreases, the level of the nonuniform sintering and the amount of crystallized cristobalite in the surface layer decrease, which is beneficial to the thermal expansion and flexural strength at ambient temperature. The flexural strength and thermal deformation at high temperature are improved by reducing the surface cracks, but deteriorated with the decrease of the cristobalite crystallization when the surface cracks are macroscopically invisible.
  • Shi-yun Dong, Xuan Zhao, Shi-xing Yan, Yao-hui Lü, Xiao-ting Liu, Yu-xin Liu, Peng He, Bin-shi Xu
    《中国铸造》英文版. 2021, 18(5): 463-473. https://doi.org/10.1007/s41230-021-1124-5
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    Direct laser deposition (DLD), as a popular metal additive manufacturing process, shows advantages of technical flexibility and high efficiency to gain a high-performance alloy steel component. However, during the processing of DLD, the deposited steel layer is affected by the subsequent layer depositing. The DLD block shows different microstructure and mechanical properties at the bottom, middle and top of the deposited parts. To date, there are few research works about the effects of inter-layer interval time and laser power on the microstructure evolution and mechanical properties of the deposited layers. In this study, the idle time and laser power layer by layer during DLD of 12CrNi2 steel were controlled to cause the deposited layers to maintain a high cooling rate, while the bottom deposited layer was subjected to a weak tempering effect. Results show that a high proportion of martensite is produced, which improves the strength of the deposited layer. Under the laser scanning strategy of laser power 2,500 W, scanning velocity 5 mm·s-1, powder feeding rate 11 g·min-1, overlap rate 50%, and a laser power difference of 50 W and a 2 min interval, the tensile strength of the deposited layer of 12CrNi2 steel is in the range of 873–1,022 MPa, and the elongation is in the range of 16.2%–18.9%. This study provides a method to reduce the tempering effect of the subsequent deposition layers on the bottom layers, which can increase the proportion of martensite in the low-alloy high-strength steel, so as to improve the yield strength of the alloy steel.
  • Shuai-bo Zhang, Yong Su, Wen-gang Gong
    《中国铸造》英文版. 2021, 18(5): 474-480. https://doi.org/10.1007/s41230-021-1020-z
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    The effects of rare earth elements (La, Sm) on the high-temperature (250 ℃) microstructure and mechanical properties of Al-Si-Cu alloys were analyzed. The experimental results show that with the addition of La and Sm, the α-Al was significantly refined, and the eutectic Si changed from acicular to rod-like and granular. XRD and SEM analysis shows that the rare earth phases in the alloy were mainly AlSiRe and AlRe. Fracture morphology observations show the fracture mode of the alloy changes from brittle and ductile fracture to ductile fracture. With the increase of La or Sm contents, the mechanical properties of the alloys at 250 ℃ increase at first, and then decrease. When the contents of La and Sm are 0.4wt.% and 0.2wt.%, the tensile strength of the alloy reaches maximum of 143.91 MPa and 201.48 MPa, respectively.
  • Xiao-yan Wu, Wei Luo, Hua-rui Zhang, Hu Zhang, Hai-tao Jiang
    《中国铸造》英文版. 2021, 18(5): 481-487. https://doi.org/10.1007/s41230-021-0137-4
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    The effect of La addition (0, 0.1, 0.2, 0.4, wt.%) on the microstructure, tensile properties and fracture behavior of Al-7Si alloy was investigated systematically. It is found that the La appears in the Al-7Si alloy in the form of Al4La and Al2Si2La phases. La addition can refine the secondary dendrite arm spacing (SDAS) and eutectic Si particles, which are decreased by 7.9% and 7%, respectively, with the optimal La content of 0.1wt.%. Because when 0.1wt.% La is added, a relatively higher nucleation undercooling of 37.47 ℃ is observed. Higher undercooling degree suggests that nucleation is accelerated and subsequent growth is restrained. After T6 heat treatment, compared with the without La, the ultimate tensile strength of the alloy with 0.1wt.% La is enhanced by 5.2% from 333 MPa to 350.2 MPa and the elongation increases by 73% from 7.37% to 12.75%, correspondingly. The fracture mode evolves from the ductile-brittle mixed fracture to ductile fracture mode. However, when La element content reaches a certain value of 0.4wt.%, serious segregation takes place during the solidification process. The formed brittle phases deteriorate the tensile properties of the alloy and the fracture mode of Al-7Si-0.2/0.4 La changes to mixed ductile-brittle fracture mode.
  • Yong Wan, Shan Gao, Meng-hua Li, Li-qiang Zhang, Yong-hong Wen, Ming-ming Song
    《中国铸造》英文版. 2021, 18(5): 488-496. https://doi.org/10.1007/s41230-021-0145-4
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    To reveal the formation mechanism and main influencing factors of C-segregation in high carbon steel under different solidification rates (40, 80, 160, 200 and 320 μm·s-1), the enrichment characteristics of carbon atoms in the solid-liquid zone of Fe-0.61%C steel were studied using a zone melting liquid metal cooling apparatus and electron probe microanalysis. The relationships among micro-segregation of carbon atoms, solid-liquid interface morphology and solidification rate were fully discussed. The results show that large dendrite spacing and a slow-moving dendritic interface create less resistance and more time for the migration of interdendritic carbon atoms to liquid zone. This results in the continuous enrichment of carbon atoms in liquid zone, further expands the solid-liquid temperature range, prolongs the solidification time of molten steel, and causes the formation of carbon micro-segregation at the solidification end as the solidification rate is 40 μm·s-1. Conversely, abundant and elongated secondary dendrite arms with small spacing seriously impede the diffusion of interdendritic carbon-rich molten steel to liquid zone. As a result, there is only obvious dendrite segregation, but little difference in the carbon content along the solidification direction as solidification rate exceeds 200 μm·s-1.
  • Bin Liu, Da-shan Sui, Zhi-min Guo, Yuan-long Wang, Xiao-lin Yang, Guang-hong Hu, Ji-xian Zhang, Chang-zeng Luo
    《中国铸造》英文版. 2021, 18(5): 497-504. https://doi.org/10.1007/s41230-021-1006-x
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    The bonding quality of bronze/steel bimetallic laminated composite is the key factor to whether it can be used in poor working conditions. In this study, bimetallic billets were prepared by the protective atmosphere casting process. The microstructural characteristics, mechanical properties and interface bonding mechanism of the bronze/steel bimetallic composites were analyzed comprehensively through a series of microstructure analysis (inicluding OM, SEM, and EDS) and mechanical properties tests. The experimental results demonstrate that the vaporization of lead (Pb) element in the bronze is only 0.4% in weight, and alloy elements are diffused into both sides at the interface. Moreover, the hardness in the bronze region exceeds 100.0 HV which indicates excellent wear resistance. Tensile and shear tests indicate that the fractures mainly occur on the bronze side with the interaction of the brittle fracture of Pb particles and the ductile fracture of Cu-Sn solid solution. The maximum tensile strength and shear strength reach 204.0 MPa and 211.0 MPa, respectively. These results demonstrate that the protective atmosphere casting process is applicable for the preparation of bronze/steel bimetallic laminated composite with high quality.
  • Long You, Chang-ji Wang, Zhou Wang, Kun-ding Liu
    《中国铸造》英文版. 2021, 18(5): 505-512. https://doi.org/10.1007/s41230-021-9012-6
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    Ti-Ni composite sub-micron powders with different compositions were prepared by vacuum melting and atomization technology. These powders, after being mixed with a solution of phenolic resin and alcohol, were applied on the mold cavity wall, by which a casting-infiltration layer was introduced on the surface of ZG45 steel via reactions between the powders and molten steel under the heat released by solidification. The effects of the powders’ composition and pouring temperature on the corrosion resistance of the casting-infiltration layer were studied. An optimal casting-infiltration layer with a thickness of ~7 mm was obtained by infiltrating the Ti-Ni composite powders containing 35wt.% Ti to ZG45 steel pouring at 1,650 ℃. The casting-infiltration layer has a good metallurgic bonding with the matrix, and is mainly composed of Fe2Ti phase and continuous γ-(Fe, Ni) solid solution. In the corrosive H2SO4 solution, the corrosion potential of the casting-infiltration layer is lower than the matrix, tending to form a passivation film, which lowers the dissolution rate especially when the potential rises to 0.50 V. After dipping in the 10wt.% NaCl solution for 480 h, a lot of corrosion holes appear in the ZG45 steel matrix, while there are no obvious traces of corrosion on the casting-infiltration layer.
  • Yi-fan Zhang, Xiao-guang Yuan, Xiao-jiao Zuo, Hong-jun Huang, Yu-lin Cheng
    《中国铸造》英文版. 2021, 18(5): 513-520. https://doi.org/10.1007/s41230-021-1078-7
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    The effect of pH value and different kinds of anions on the corrosion behavior of Cu/Al casting-rolled clad plates in the alkaline solution was evaluated by means of scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), weight loss analysis, 3D confocal laser scanning microscopy (CLSM) and electrochemical test. Results show the corrosion mainly occurs on the aluminum side. The corrosion resistance of the Cu/Al decreases as the pH value increases. When pH≥12, the dissolution of the film layer is faster than the passivation process. The addition of Cl- ions reduces the corrosion resistance of the Cu/Al clad plates, which leads to pitting corrosion. The higher the concentration of Cl- ions, the more prone the pitting to occur. The addition of SO42- ions causes the denudation of the samples. The corrosion resistance of the Cu/Al is better in the alkaline solution containing NO3- ions than that in the solution containing Cl- ions or SO42- ions. When adding SO42-, NO3- and Cl- to the pure alkaline solution, the corrosion resistance of the Cu/Al clad plates decreases.