对TC4钛合金进行了低压电子束熔丝沉积试验,探究了该方法的可行性,并分析了沉积层数对微观组织和性能的影响. 结果表明,在加速电压为10 kV的低压时也可完成TC4钛合金的多层熔丝沉积. 多层沉积之后得到的沉积件的平均显微硬度在260 HV左右,只有沉积件底部条带状纹理聚集处的显微硬度接近退火态TC4基材的288 HV. 条带状纹理产生于多层沉积的过程之中,β相晶粒受热循环影响而发生了β → α + α' + β的转变,其中硬度较高的网篮状α'相与片状的α相组成了条带状纹理,该显微组织的特点是随着与基板距离的增加,网篮状组织逐渐融入片状组织. 沉积件的拉伸断裂形式为韧性断裂,最高抗拉强度为862 MPa,略低于国家标准,这是因为在多层沉积的沉积件中β柱状晶会变得巨大,同时还会出现等轴晶,晶粒的巨大化使得沉积件的抗拉性能出现了下降.
The low voltage electron beam wire deposition tests on TC4 titanium alloy were carried out to explore the feasibility of the method, and the influence of the number of deposited layers on the microstructure and properties was analyzed. The results show that the multi-layer wire deposition of TC4 titanium alloy can also be completed on the accelerated voltage of 10 kV. The average microhardness of the deposited parts after multi-layer deposition is about 260 HV, and only the microhardness of the banded texture at the bottom of the deposited parts is close to 288 HV of the annealed TC4 substrate. Banded texture produced in multi-layer deposition process, β phase grain transformed to α + α' + β by the influence of thermal cycle, the banded texture which composited with basket-like α' phase and lamellar α phase have high microhardness, the other feature of banded texture is that more basket-like phase gradually integrated into the lamellar structure as the increase of the distance with substrate. The tensile fracture of the deposited part is also ductile fracture with the maximum tensile strength of 862 MPa, which is slightly lower than the national standard. It because the columnar crystals will become huge in the deposited parts with multiple layers, and equiaxed crystals will also appear. The huge size of the grains will decrease the tensile properties of the deposited parts.
[1] Liu X Y, Chu P K, Ding C X. Surface modification of titanium, titanium alloys, and related materials for biomedical applications[J]. Materials Science & Engineering. R, Reports, 2004, 47(3-4): 49 - 121.
[2] Zhang W G, Wang C G, Liu W M. Characterization and tribological investigation of sol-gel ceramic films on Ti-6Al-4V[J]. Wear, 2006, 260(4-5): 379 - 386.
[3] Dandekar C, Shin Y, Barnes J. Machinability improvement of titanium alloy (Ti-6Al-4V) via LAM and hybrid machining[J]. International Journal of Machine Tools and Manufacture, 2010, 50(2): 174 - 182.
[4] 赵剑峰, 马智勇, 谢德巧, 等. 金属增材制造技术[J]. 南京航空航天大学学报, 2014, 46(5): 675 - 683
Zhao Jianfeng, Ma Zhiyong, Xie Deqiao, et al. Metal additive manufacturing technology[J]. Journal of Nanjing University of Aeronautics & Astronautics, 2014, 46(5): 675 - 683
[5] Colegrove P, Coules H E, Fairman J, et al. Microstructure and residual stress improvement in wire and arc additively manufactured parts through high-pressure rolling[J]. Journal of Materials Processing Technology, 2013, 213(10): 1782 - 1791.
[6] Thijs L, Verhaeghe F, Craeghs T, et al. A study of the microstructural evolution during selective laser melting of Ti-6Al-4V[J]. Acta Materialia, 2010, 58(9): 3303 - 3312.
[7] 王华明. 高性能大型金属构件激光增材制造: 若干材料基础问题[J]. 航空学报, 2014, 35(10): 2690 - 2698
Wang Huaming. Laser additive manufacturing of high-performance large metal components: some material foundation issues[J]. Acta Aeronautica ET Astronautica Sinica, 2014, 35(10): 2690 - 2698
[8] Stecker S, Lachenberg KW, Wang H, et al. Advanced electron beam free form fabrication methods & technology[J]. Session, 2006(2): 35 - 46.
[9] 邓贤辉, 杨治军. 钛合金增材制造技术研究现状及展望[J]. 材料开发与应用, 2014, 29(5): 113 - 120
Deng Xianhui, Yang Zhijun. Research status and development of additive manufacturing technology of titanium alloy[J]. Development and Application of Materials, 2014, 29(5): 113 - 120
[10] 黄志涛, 巩水利, 锁红波, 等. 电子束熔丝成形的TC4钛合金的组织与性能研究[J]. 钛工业进展, 2016, 33(5): 33 - 36
Huang Zhitao, Gong Shuili, Suo Hongbo, et al. Study on microstructure and properties of TC4 titanium alloy formed by electron beam fuse[J]. Advances in Titanium Industry, 2016, 33(5): 33 - 36