采用复合钎料加压钎焊70%SiCp/Al复合材料

  • 张德库 ,
  • 王恒 ,
  • 康路路 ,
  • 孙彪
展开
  • 南京理工大学,南京,210094
张德库,1971年出生,博士,副教授;主要从事先进材料连接方面的研究;发表论文40余篇;Email:zdk@njust.edu.cn.

收稿日期: 2019-03-22

  网络出版日期: 2020-09-27

基金资助

国防科技创新特区项目(18–H863-03-ZD-007-004-02)

Pressure brazing of 70% SiCp / Al composites using composite fillers

  • ZHANG Deku ,
  • WANG Heng ,
  • KANG Lulu ,
  • SUN Biao
Expand
  • Nanjing Uniwersity of Science and Technology, Naijing, 210094, China

Received date: 2019-03-22

  Online published: 2020-09-27

摘要

采用机械球磨的方法制备了Al-Si-xSiC(x为体积分数)复合钎料,采用复合钎料实现了70%SiCp/Al复合材料的加压钎焊连接. 利用SEM和EDS确定了钎缝是由α-Al,Si,SiC,Al2O3等相组成. 结果表明,在压力作用下SiC颗粒被固定在钎缝区而使得钎缝区的组织类似于复合材料,钎缝中一定的SiC颗粒可以缓解母材与金属钎料之间的热膨胀系数之差,从而减小了焊接残余应力,可以提高接头的强度,而钎焊施加一定的压力则可促进钎料与SiC颗粒的润湿性. 工艺适当时,接头最高强度达到125.7 MPa.

本文引用格式

张德库 , 王恒 , 康路路 , 孙彪 . 采用复合钎料加压钎焊70%SiCp/Al复合材料[J]. 焊接学报, 2020 , 41(6) : 67 -71 . DOI: 10.12073/j.hjxb.20190322003

Abstract

The Al-Si-xSiC(x is the volume fraction) composite fillers were prepared by mechanical ball-milling method, in order to achieve a connection of 70% SiCp /Al composites using pressure brazing. The joints are composed of α-Al, Si, SiC, Al2O3 and other phase identified by SEM and EDS. The results showed that SiC particles are pinned in the seam which is similar to composites under pressure. Difference of coefficient of thermal expansion between the base metal and the fillers can be alleviated by certain SiC particles in the seam, thereby welding residual stress was reduced, and the strength of the joint was enhanced. In addition, the wetting of fillers and SiC particles can be promoted by a certain pressure during brazing.

参考文献

[1] Çevik E, Sun Y, Ahlatci H, et al. Effect of magnesium additions on composites with Al and Al-12% Si matrices strengthened with B4C and prepared by infiltration under pressure[J]. Metal Science & Heat Treatment, 2016, 58(5-6): 1-5.
[2] Yolshina L. Novel aluminum-graphene and aluminum-graphite metallic composite materials: synthesis and properties[J]. Journal of Alloys & Compounds, 2016, 663: 449-459.
[3] Sharma V, Prakash U, Kumar B V M. Surface composites by friction stir processing: a review[J]. Journal of Materials Processing Technology, 2015, 224: 117-134.
[4] Zhang D, Zhan Z. Strengthening effect of graphene derivatives in copper matrix composites[J]. Journal of Alloys and Compounds, 2016, 654: 226-233.
[5] Springer H, Aparicio Fernandez R, Duarte M J, et al. Microstructure refinement for high modulus in-situ metal matrix composite steels via controlled solidification of the system Fe-TiB2[J]. Acta Materialia, 2015, 96: 47-56.
[6] Reeb A, Merzkirch M, Schulze V, et al. Heat treatment during composite extruded spring steel wire reinforced EN AW-6082[J]. Journal of Materials Processing Technology, 2016, 229: 1-8.
[7] 李娟, 王克鸿, 张德库. 合金元素对70%SiCp/Al复合材料钎料性能的影响[J]. 焊接学报, 2015, 36(10): 73-76,104
Li Juan, Wang Kehong, Zhang Deku. Effect of alloying elements on the 70% SiCp/Al composites solder properties[J]. Transactions of the China Welding Institution, 2015, 36(10): 73-76,104
[8] 娄菊红, 杨延清, 原梅妮, 等. 金属基复合材料界面残余应力的研究进展[J]. 材料导报, 2009, 23(19): 75-78
Lou Juhong, Yang Yanqing, Yuan Meini, et al. Research progress on interfacial residual stress of metal matrix composites[J]. Materials Reports, 2009, 23(19): 75-78
[9] 邰枫, 郭福, 申灏, 等. 纳米Ag颗粒增强复合钎料蠕变性能的研究[J]. 稀有金属材料与工程, 2010, 39(6): 1005-1008
Tai Feng, Guo Fu, Shen Hao, et al. Study on creep properties of Ag nanoparticles reinforced Sn-Cu composite solder[J]. Rare Metal Materials and Engineering, 2010, 39(6): 1005-1008
[10] 杨俊, 吴爱萍, 邹贵生, 等. TiN改性钎料连接Si3N4陶瓷的接头高温性能[J]. 焊接学报, 2006, 27(7): 18-20
Yang Jun, Wu Aiping, Zou Guisheng, et al. The high temperature performance of TiN modified solder joint connection Si3N4 ceramic[J]. Transactions of the China Welding Institution, 2006, 27(7): 18-20
[11] Zhu M, Chung D D L. Improving the strength of brazed joints to alumina by adding carbon fibres[J]. Journal of Materials Science, 1997, 32(20): 5321-5333.
[12] 宋晓国, 曹健, 陈海燕, 等. 颗粒增强复合钎料钎焊TiAl合金接头界面结构及性能[J]. 焊接学报, 2013, 34(7): 13-16
Song Xiaoguo, Cao Jian, Chen Haiyan, et al. Interface structure and properties of TiAl alloy joints brazed by particle reinforced composite brazing filler metal[J]. Transactions of the China Welding Institution, 2013, 34(7): 13-16
[13] 康路路. 高体积分数SiCp/Al复合材料钎接-扩散复合连接工艺研究[D]. 南京:南京理工大学, 2016.
Kang Lulu. Research on Brazing and diffusion bonding welding technology of SiCp/Al composite materials[D]. Nanjing: Nanjing University of Science and Technology, 2016.
文章导航

/