Smart Materials

Mesoporous TiO2 Nanofiber as Highly Efficient Sulfur Host for Advanced Lithium–Sulfur Batteries

  • Xinyu Shan ,
  • Zuoxing Guo ,
  • Xu Zhang ,
  • Jie Yang ,
  • Lianfeng Duan
Expand
  • 1. Key Laboratory of Automobile Materials, School of Materials Science and Engineering, Jilin University, Changchun 130025, China;
    2. Advanced Institute of Materials Science & Department of Materials Science and Engineering, Changchun University of Technology, Changchun 130012, China

Received date: 2019-05-25

  Revised date: 2019-06-20

  Online published: 2019-09-24

Supported by

Supported by National Nature Science Foundation of China (Grant No. 61774022) and Education Department of Jilin Province of China (Grant No. JJKH20181030KJ)

Abstract

Currently, lithium-sulfur batteries suffer from several critical limitations that hinder their practical application, such as the large volumetric expansion of electrode, poor conductivity and lower sulfur utilization. In this work, TiO2 nanofibers with mesoporous structure have been synthesized by electrospinning and heat treating. As the host material of cathode for Li-S battery, the as prepared samples with novelty structure could enhance the conductivity of cathode composite, promote the utilization of sulfur, and relieve volume expansion for improving the electrochemical property. The initial discharge capacity of TiO2/S composite cathode is 703 mAh/g and the capacity remained at 652 mAh/g after 200 cycles at 0.1 C, whose the capacity retention remains is at 92.7%, demonstrating great prospect for application in high-performance Li-S batteries.

Cite this article

Xinyu Shan , Zuoxing Guo , Xu Zhang , Jie Yang , Lianfeng Duan . Mesoporous TiO2 Nanofiber as Highly Efficient Sulfur Host for Advanced Lithium–Sulfur Batteries[J]. Chinese Journal of Mechanical Engineering, 2019 , 32(4) : 60 -60 . DOI: 10.1186/s10033-019-0374-2

References

[1] X L He, H Hou, X Yuan, et al. Electrocatalytic activity of lithium polysulfides adsorbed into porous TiO2 coated MWCNTs hybrid structure for lithium-sulfur batteries. Scientific Reports, 2017, 7: 40679-40687.
[2] C L Wang, K Li, F F Zhang, et al. Insight of enhanced redox chemistry for porous MoO2 carbon-derived framework as polysulfide reservoir in lithium-sulfur batteries. ACS Appl. Mater. Interfaces, 2018, 10: 42286-42293.
[3] G M Liang, J X Wu, X Y Qin, et al. Ultrafine TiO2 decorated carbon nanofibers as multifunctional interlayer for high performance lithium-sulfur battery. ACS Appl. Mater. Interfaces, 2016, 8: 23105-23113.
[4] R P Fang, S Y Zhao, S F Pei, et al. Toward more reliable lithium-sulfur batteries: An all-graphene cathode structure. ACS Nano, 2016, 10: 8676-8682.
[5] X Z Ma, B Jin, H Y Wang, et al. S-TiO2 composite cathode materials for lithium/sulfur batteries. J. Electroanal. Chem., 2015, 736: 127-131.
[6] K Mi, Y Jiang, J K Feng, et al. Hierarchical carbon nanotubes with a thick microporous wall and inner channel as efficient scaffolds for lithium-sulfur batteries. Adv. Funct. Mater., 2016, 26: 1571-1579.
[7] G X Li, J H Sun, W P Hou, et al. Three-dimensional porous carbon composites containing high sulfur nanoparticle content for high-performance lithium-sulfur batteries. Nat. Commun., 2016, 7: 10601.
[8] B Ding, L Shen, G Xu, et al. Encapsulating sulfur into mesoporous TiO2 host as a high performance cathode for lithium-sulfur battery. Electrochimica Acta, 2013, 107: 78-84.
[9] F F Zhang, S P Huang, X Wang, et al. Redox-targeted catalysis for vanadium redox-flow batteries. Nano Energy, 2018, 52: 292-299.
[10] K Z Cao, H Q Liu, Y Li, et al. Encapsulating sulfur in δ-MnO2 at room temperature for Li-S battery cathode. Energy Storage Materials, 2017, 9: 78-84.
[11] H C Wang, C Y Fan, Y P Zeng, et al. Oxygen-deficient titanium dioxide nanosheets as more effective polysulfide reservoirs for lithium-sulfur batteries. Chem. Eur., 2017, 23: 9666-9673.
[12] X G Han, Y H Xu, X Y Chen, et al. Reactivation of dissolved polysulfides in Li-S batteries based on atomic layer deposition of Al2O3 in nanoporous carbon cloth. Nano Energy, 2013, 2: 1197-1206.
[13] H W Zhu, Y K Jing, M Pal, et al. Mesoporous TiO2@ N-doped carbon composite nanospheres synthesized by the direct carbonization of surfactants after sol-gel process for superior lithium storage. Nanoscale, 2017, 9: 1539-1546.
[14] F F Zhang, C L Wang, G Huang, et al. FeS2@C nanowires derived from organic-inorganic hybrid nanowires for high-rate and long-life lithium-ion batteries. J. Power Sources, 2016, 328: 56-64.
[15] G G Hu, C Xu, Z H Sun, et al. 3D graphene-foam-reduced-graphene-oxide hybrid nested hierarchical networks for high-performance Li-S batteries. Adv. Mater., 2016, 28: 1603-1609.
[16] Y L An, Z Zhang, H F Fei, et al. Ultrafine TiO2 confined in porous-nitrogen-doped carbon from metal-organic frameworks for high-performance lithium sulfur batteries. ACS Appl. Mater. Interfaces, 2017, 9: 12400-12407.
[17] Z W Seh, W Y Li, J J Cha, et al. Sulphur-TiO2 yolk-shell nanoarchitecture with internal void space for long-cycle lithium-sulphur batteries. Nat. Commun., 2013, 4: 1331.
[18] J Y Li, B Ding, G Y Xu, et al. Enhanced cycling performance and electrochemical reversibility of a novel sulfur-impregnated mesoporous hollow TiO2 sphere cathode for advanced Li-S batteries. Nanoscale, 2013, 5: 5743-5746.
[19] J S Cho, Y J Hong, Y C Kang. Electrochemical properties of fiber-in-tube- and filled-structured TiO2 nanofiber anode materials for lithium-ion batteries. Chem. Eur., 2015, 21: 11082-11087.
[20] D Zheng, J Xiong, P Guo, et al. Fabrication of improved dye-sensitized solar cells with anatase/rutile TiO2 nanofibers. Nanosci. Nanotechnol., 2016, 16: 613-618.
[21] K Mondal, M A Ali, V V Agrawal, et al. Highly sensitive biofunctionalized mesoporous electrospun TiO2 nanofiber based interface for biosensing. ACS Appl. Mater. Interfaces, 2014, 6: 2516-2527.
[22] Z A Zhang, Q Li, S F Jiang, et al. Sulfur encapsulated in a TiO2-anchored hollow carbon nanofiber hybrid nanostructure for lithium-sulfur batteries. Chem. Eur., 2015, 21: 1343-1349.
[23] Y Y Li, Q F Cai, L Wang, et al. Mesoporous TiO2 nanocrystals/ graphene as an efficient sulfur host. ACS Appl. Mater. Interfaces, 2016, 8: 23784-23792.
[24] Z Z Yang, H Y Wang, L Lu, et al. Hierarchical TiO2 spheres as highly efficient polysulfide host for lithium-sulfur batteries. Sci. Rep., 2016, 6: 22990-22998.
[25] J Cao, C Chen, Q Zhao, et al. A flexible nanostructured paper of a reduced graphene oxide-sulfur composite for high-performance lithium-sulfur batteries with unconventional configurations. Adv. Mater., 2016, 28: 9629-9636.
[26] J K Wang, K Q Yue, X D Zhu, et al. C-S@PANI composite with a polymer spherical network structure for high performance lithium-sulfur batteries. Physical Chemistry Chemical Physics, 2016, 18: 261-266.
[27] J Li, J Q Guo, J N Deng, et al. Enhanced electrochemical performance of lithium-sulfur batteries by using mesoporous TiO2 spheres as host materials for sulfur impregnation. Materials Letters, 2017, 189: 188-191.
[28] Q Zhao, X F Hu, K Zhang, et al. Sulfur nanodots electrodeposited on Ni foam as high-performance cathode for Li-S batteries. Nano Lett., 2015, 15: 721-726.
[29] G M Zhou, Y B Zhao, C X Zu, et al. Free-standing TiO2 nanowire-embedded graphene hybrid membrane for advanced Li/dissolved polysulfide batteries. Nano Energy, 2015, 12: 240-249.
Outlines

/