Smart Materials

Preparation of Nickel-Cobalt/Carborundum Carbide Composite Coatings by Supergravity Field-Enhanced Electrodeposition

  • Xiaoyun Hu ,
  • Ningsong Qu
展开
  • 1. Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China;
    2. Jiangsu Key Laboratory of Precision and Micro-Manufacturing Technology, Nanjing 210016, China

收稿日期: 2019-12-26

  修回日期: 2020-07-17

  网络出版日期: 2020-11-06

基金资助

Supported by National Key Research and Development Program of China (Grant No. 2018YFB1105900), National Basic Research Program of China (973 Program, Grant No. 2015CB057502), and Fundamental Research Funds for the Central Universities (Grant No. NZ2016106)

Preparation of Nickel-Cobalt/Carborundum Carbide Composite Coatings by Supergravity Field-Enhanced Electrodeposition

  • Xiaoyun Hu ,
  • Ningsong Qu
Expand
  • 1. Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China;
    2. Jiangsu Key Laboratory of Precision and Micro-Manufacturing Technology, Nanjing 210016, China

Received date: 2019-12-26

  Revised date: 2020-07-17

  Online published: 2020-11-06

Supported by

Supported by National Key Research and Development Program of China (Grant No. 2018YFB1105900), National Basic Research Program of China (973 Program, Grant No. 2015CB057502), and Fundamental Research Funds for the Central Universities (Grant No. NZ2016106)

摘要

Nickel-cobalt/silicon carbide (Ni-Co/SiC) composite coatings were fabricated by supergravity field-enhanced electrodeposition. The surface morphology and the distribution of the SiC particles in the coatings were examined by scanning electron microscope and energy dispersive X-ray spectrometry. The preferred orientations of the coatings were measured by X-ray diffractometry. The wear resistance and microhardness were measured by a reciprocating tribometer and a microhardness instrument, respectively. The results revealed that the use of the supergravity field enhanced the smoothness of the as-deposited Ni-Co/SiC coatings, and the SiC nanoparticles were uniformly distributed in comparison with that for conventional electrodeposition. When the rotation speed of the cathode, which provided the supergravity field, was 800 r/min, the SiC content in the coating reached a maximum of 8.1 wt%, which was a much higher content than the 2.2 wt% value obtained under conventional electrodeposition. The highest coating microhardness of 680 HV was also observed at this rotation speed. In addition, the wear resistance of the as-prepared Ni-Co/SiC coatings exhibited improved performance relative to that prepared under normal gravity. A minimum wear weight loss of 1.4 mg together with an average friction coefficient of 0.13 were also realized at a rotation speed of 800 r/min, values which were much lower than those for normal gravity.

本文引用格式

Xiaoyun Hu , Ningsong Qu . Preparation of Nickel-Cobalt/Carborundum Carbide Composite Coatings by Supergravity Field-Enhanced Electrodeposition[J]. Chinese Journal of Mechanical Engineering, 2020 , 33(4) : 57 -57 . DOI: 10.1186/s10033-020-00478-8

Abstract

Nickel-cobalt/silicon carbide (Ni-Co/SiC) composite coatings were fabricated by supergravity field-enhanced electrodeposition. The surface morphology and the distribution of the SiC particles in the coatings were examined by scanning electron microscope and energy dispersive X-ray spectrometry. The preferred orientations of the coatings were measured by X-ray diffractometry. The wear resistance and microhardness were measured by a reciprocating tribometer and a microhardness instrument, respectively. The results revealed that the use of the supergravity field enhanced the smoothness of the as-deposited Ni-Co/SiC coatings, and the SiC nanoparticles were uniformly distributed in comparison with that for conventional electrodeposition. When the rotation speed of the cathode, which provided the supergravity field, was 800 r/min, the SiC content in the coating reached a maximum of 8.1 wt%, which was a much higher content than the 2.2 wt% value obtained under conventional electrodeposition. The highest coating microhardness of 680 HV was also observed at this rotation speed. In addition, the wear resistance of the as-prepared Ni-Co/SiC coatings exhibited improved performance relative to that prepared under normal gravity. A minimum wear weight loss of 1.4 mg together with an average friction coefficient of 0.13 were also realized at a rotation speed of 800 r/min, values which were much lower than those for normal gravity.

参考文献

[1] K Ignatova, Y Marcheva. Composition and structure of Ni-Co coating depending on the ratio of Ni and Co in a citrate electrolyte. Bulgarian Chemical Communications, 2017, 49(2): 313-319.
[2] A Sivanantham, P Ganesan, S Shanmugam. Hierarchical NiCo2S4 nanowire arrays supported on Ni foam: an efficient and durable bifunctional electrocatalyst for oxygen and hydrogen evolution reactions. Advanced Functional Materials, 2016, 26(26): 4661-4672.
[3] C Du, L Yang, F Yang, et al. Nest-like NiCoP for highly efficient overall water splitting. ACS Catalysis, 2017, 7(6): 4131-4137.
[4] J De, T Banerjee, R S Sen, et al. Multi-objective optimization of electroless ternary Nickel-Cobalt-Phosphorous coating using non-dominant sorting genetic algorithm-Ⅱ. Engineering Science and Technology, An International Journal, 2016, 19(3): 1526-1533.
[5] A Karimzadeh, M Aliofkhazraei, F C Walsh. A review of electrodeposited Ni-Co alloy and composite coatings: Microstructure, properties and applications. Surface and Coatings Technology, 2019, 372: 463-498.
[6] Y J Chang, C H Chang. Intelligent computation for optimal fabrication condition of a protein chip with Ni-Co alloy-coated surface. Journal of Laboratory Automation, 2016, 21(3): 394-401.
[7] S M L Baghal, A Amadeh, M H Sohi, et al. The effect of SDS surfactant on tensile properties of electrodeposited Ni-Co/SiC nanocomposites. Materials Science and Engineering A-Structural Materials Properties Microstructure and Processing, 2013, 559: 583-590.
[8] C Ma, S Wang, F C Walsh. The electrodeposition of nanocrystalline Cobalt-Nickel-Phosphorus alloy coatings: A review. Transactions of the IMF, 2015, 93(5): 275-280.
[9] B Bakhit, A Akbari. A comparative study of the effects of saccharin and β-SiC nano-particles on the properties of Ni and Ni-Co alloy coatings. Surface and Coatings Technology, 2014, 253: 76-82.
[10] A Rasooli, M S Safavi, M K Hokmabad. Cr2O3 nanoparticles: A promising candidate to improve the mechanical properties and corrosion resistance of Ni-Co alloy coatings. Ceramics International, 2018, 44(6): 6466-6473.
[11] A Al-Fatesh. Suppression of carbon formation in CH4-CO2 reforming by addition of Sr into bimetallic Ni-Co/γ-Al2O3 catalyst. Journal of King Saud University - Engineering Sciences, 2015, 27(1): 101-107.
[12] X H Wang, B Lu, Z F Hu, et al. Effects of n-Al2O3 particles content on structure and performance of electro-brush plating Ni-Co alloy composite coatings. Rare Metal Materials and Engineering, 2016, 45(1): 36-41.
[13] A W J Hsue, Y F Chang. Toward synchronous hybrid micro-EDM grinding of micro-holes using helical taper tools formed by Ni-Co/diamond Co-deposition. Journal of Materials Processing Technology, 2016, 234: 368-382.
[14] P R Dheeraj, A Patra, S Sengupta, et al. Synergistic effect of peak current density and nature of surfactant on microstructure, mechanical and electrochemical properties of pulsed electrodeposited Ni-Co-SiC nanocomposites. Journal of Alloys and Compounds, 2017, 729: 1093-1107.
[15] B Bakhit. The influence of electrolyte composition on the properties of Ni-Co alloy coatings reinforced by SiC nano-particles. Surface and Coatings Technology, 2015, 275: 324-331.
[16] C Y Ma, D Q Zhao, Z P Ma. Effects of duty cycle and pulse frequency on microstructures and properties of electrodeposited Ni-Co-SiC nanocoatings. Ceramics International, 2012, 46(8): 12128-12137.
[17] W Jiang, L D Shen, M Y Xu, et al. Mechanical properties and corrosion resistance of Ni-Co-SiC composite coatings by magnetic field-induced jet electrodeposition. Journal of Alloys and Compounds, 2019, 791: 847-855.
[18] B Bakhit, A Akbari. Effect of particle size and co-deposition technique on hardness and corrosion properties of Ni-Co/SiC composite coatings. Surface and Coatings Technology, 2012, 206(23): 4964-4975.
[19] H K Lee, H Y Lee, J M Jeon. Codeposition of micro- and nano-sized SiC particles in the nickel matrix composite coatings obtained by electroplating. Surface and Coatings Technology, 2007, 201(8): 4711-4717.
[20] W Wang, F Y Hou, H Wang, et al. Fabrication and characterization of Ni-ZrO2 composite nano-coatings by pulse electrodeposition. Scripta Materialia, 2005, 53(5): 613-618.
[21] N Zhang, Z Wang, L Guo, et al. Rapid fabrication of W-Cu composites via low-temperature infiltration in supergravity fields. Journal of Alloys and Compounds, 2019, 809: 151782.
[22] N Zhang, Z Wang, L Guo, et al. Supergravity process for enriching and separating Ag from Sn-Ag-Zn melts. Chemical Engineering and Processing - Process Intensification, 2019, 143: 107591.
[23] X C Yin, G Sun, A L Song, et al. A novel structure of Ni-(MoS2/GO) composite coatings deposited on Ni foam under supergravity field as efficient hydrogen evolution reaction catalysts in alkaline solution. Electrochimica Acta, 2017, 249: 52-63.
[24] A Murotani, T Fuchigami, M Atobe. Electrochemical deposition of Ni/SiC under centrifugal fields. Electrochemistry, 2008, 76(11): 824-826.
[25] X Y Hu, N S Qu. Improved corrosion resistance of Ni-Co coatings prepared by electrodeposition with large centrifugal acceleration. Journal of Materials Engineering and Performance, 2019, 28(4): 2104-2114.
[26] X Y Hu, N S Qu. Enhanced corrosion resistance of nickel-cobalt/carborundum coatings formed by supergravity field-assisted electrodeposition. Thin Solid Films, 2020, 700: 137923.
[27] M Srivastava, V K W Grips, K S Rajam. Electrodeposition of Ni-Co composites containing nano-CeO2 and their structure, properties. Applied Surface Science, 2010, 257(3): 717-722.
[28] J S Chen, Y H Huang, Z D Liu. Jet electrodeposition oriented by rapid prototyping. Transactions of Nonferrous Metals Society of China, 2005, 15(3): 247-250.
[29] W Jiang, L D Shen, M B Qiu, et al. Preparation of Ni-SiC composite coatings by magnetic field-enhanced jet electrodeposition. Journal of Alloys and Compounds, 2018, 762: 115-124.
[30] N Guglielmi. Kinetics of the deposition of inert particles from electrolytic baths. Journal of the Electrochemical Society, 1972, 119(8): 1009.
[31] D D Ning, A Zhang, M Murtaza, et al. Effect of surfactants on the electrodeposition of Cu-TiO2 composite coatings prepared by jet electrodeposition. Journal of Alloys and Compounds, 2019, 777: 1245-1250.
[32] F T L Muniz, M A Miranda, C M Santos, et al. The Scherrer equation and the dynamical theory of X-ray diffraction. Acta Cryst., 2016, 72(3): 385-390.
[33] L Benea, P L Bonora, A Borello, et al. Preparation and investigation of nanostructured SiC-nickel layers by electrodeposition. Solid State Ionics, 2002, 151(1-4): 89-95.
[34] N P Wasekar, L Bathini, G Sundararajan. Tribological behavior of pulsed electrodeposited Ni-W/SiC nanocomposites. Journal of Materials Engineering and Performance, 2018, 27(10): 5236-5245.
[35] J Hu, Y N Shi, X Sauvage, et al. Grain boundary stability governs hardening and softening in extremely fine nanograined metals. Science, 2017, 355 (6331): 1292-1296.
[36] Y J Xue, W Ma, J S Li, et al. Fabrication and wear resistance of Ni-CeO2 nanocomposite coatings by electrodeposition under ultrasound condition. Advanced Tribology, 2010, 3: 202-313.
[37] A A P Sidharth, I Sridhar. Material removal analysis for compliant polishing tool using adaptive meshing technique and Archard wear model. Wear, 2019, 418: 140-150.
[38] S Dehgahi, R Amini, M Alizadeh. Corrosion, passivation and wear behaviors of electrodeposited Ni-Al2O3-SiC nanocomposite coatings. Surface and Coatings Technology, 2016, 304: 502-511.
文章导航

/