20 March 2022, Volume 46 Issue 3
    

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    Technical Review
  • MIAO Keji, LIU Jianfeng, YIN Yangyang, WANG Ting, LIU Chuanhuai, YUAN Binxia, PAN Weiguo, YIN Shibin
    Materials For Mechanical Engineering. 2022, 46(3): 1-6,12. https://doi.org/10.11973/jxgccl202203001
    Abstract ( ) Download PDF ( )   Knowledge map   Save
    The microstructure evolution, formation and propagation of type Ⅳ cracks, and creep rupture mechanism of ferritic/austenitic steel welded joints in thermal power plant during service are reviewed. The creep rupture behavior of weak position of the welded joints is emphatically analyzed. The influencing factors of creep rupture in the heat-affected zone of ferritic steel are summarized, and relevant suggestions for improving the creep performance of welded joints are given. Finally, the future research direction is prospected.
  • Testing & Research
  • CHEN Meng, WU Riming
    Materials For Mechanical Engineering. 2022, 46(3): 7-12. https://doi.org/10.11973/jxgccl202203002
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    Referring to the chemical composition of 4Cr5Mo2V hot-work die steel, test steels with V mass fraction of 0, 0.55% and 0.9% were prepared, and surface ion nitriding treatment was carried out. The effect of V content on the microstructure and properties of hot-work die steel after nitriding was studied. The results show that the matrix structures of three test steels were all martensite, and the nitriding layer was mainly composed of white bright layer and diffusion layer. With increasing V content, the matrix structure of test steel was obviously refined, the distribution of white bright layer became continuous, and the thickness of diffusion layer first increased and then decreased. When the V content was 0.55wt%, the matrix structure was the finest and the diffusion layer was the thickest. Fine granular precipitates rich in C, N, Cr and V appeared in diffusion layer after added V. As the V content increased to 0.9wt%, the number of precipitates decreased and the size increased. The surface hardness and wear resistance of test steels increased first and then decreased with increasing V content. When the V content was 0.55wt%, the surface hardness was the highest, 1 287.3 HV, the friction coefficient was the lowest, 0.15, and the wear mechanism was abrasive wear.
  • MING Meihua, WANG Linda, ZHOU Feng, ZHANG Yong
    Materials For Mechanical Engineering. 2022, 46(3): 13-18,24. https://doi.org/10.11973/jxgccl202203003
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    Poly(L-lactic acid) (PLLA)/poly(butylene adipate-co-terephthalate) (PBAT) (80/20, parts by mass)blend was prepared by melting blending. The effect of adding 1 part by mass of chain extender ADR and 1 part by mass of nucleating agent LAK on the crystallization behavior, mechanical properties, rheological behavior and thermal stability of PLLA/PBAT blend were investigated. The results show that after adding chain extender ADR, the crystallinity of PLLA/PBAT blend decreased, while the toughness and impact strength increased, and the compatibility between PLLA and PBAT was improved. After further adding nucleating agent LAK, the crystallinity of the blend increased significantly, the elongation at break and impact strength decreased, but the blend still had good toughness. Chain extender ADR improved the molding processability and heat resistance of the blend, while the improvement effect decreased slightly after further adding nucleating agent LAK. After adding chain extender ADR and nucleating agent LAK simultaneously, PLLA/PBAT blend had both high crystallinity and good properties at the same time.
  • CAI Jiakun, WU Jisi, LI Xiaoyang, YANG Chenggang, ZHANG Qiang
    Materials For Mechanical Engineering. 2022, 46(3): 19-24. https://doi.org/10.11973/jxgccl202203004
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    Copper/polyimide resin matrix composites with a total mass fraction of 20% SiC and WS2 were prepared by powder metallurgy, and the mass ratios of WS2 to SiC were 1:3, 3:5, 1:1, 5:3, and 3:1, respectively. The effect of the mass ratio of solid lubricant WS2 and reinforced phase SiC on the micromorphology and friction and wear properties of the composites was studied. The results show that when the mass ratio of WS2 to SiC was 3:5, a core-shell structure with WS2 particles as the core and SiC particles as the shell began to form in the composite. With increasing the mass ratio of WS2 to SiC, the core-shell structure changed from flat to circular, and its number and area increased; the friction and wear properties increased first and then decreased, and the wear mechanism changed from abrasive wear to fatigue wear, and finally to severe abrasive wear. When the mass ratio of WS2 to SiC was 5:3, the friction and wear properties of the composite were the best.
  • YIN Xuzhong, LI Heng, TANG Jianqun, GONG Jianming
    Materials For Mechanical Engineering. 2022, 46(3): 25-30,37. https://doi.org/10.11973/jxgccl202203005
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    The corrosion behaviors of 304 and 316L austenitic stainless steel immersed in molten nitrate salt (60% NaNO3 + 40% KNO3,mass fraction) with different mass fraction (0,0.6%,1.0%,1.4%) of chloride ion impurity at 565℃ were studied using constant temperature immersion corrosion test method. The results show that 304 and 316L stainless steel in four types of molten nitrate salts exhibited parabolic corrosion kinetic. With increasing chloride content, the corrosion rate of 304 and 316L stainless steel increased significantly, the corrosion degree gradually increased, and the cracks of the corrosion product layer at the junction with the substrate increased. Chloride ion impurities accelerated the corrosion of stainless steel through active oxidative corrosion. Compared with 316L stainless steel, 304 stainless steel was more sensitive to the corrosive effect of chloride ion impurities.
  • HUA Xin, WANG Wei, XIAO Ming, YAO Lili
    Materials For Mechanical Engineering. 2022, 46(3): 31-37. https://doi.org/10.11973/jxgccl202203006
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    Electroplating process was used to galvanize the surface of C72D2 steel wire, and the mass of the coating per unit area was 45 g·m-2. The thermal diffusion treatment was carried out at different temperatures (450-550℃), and the galvanized steel wire was drawn into monofilament by wet drawing process. The effects of thermal diffusion temperature on the structure of the coating, the tensile strength and rotating bending fatigue performance of monofilament were studied. By comparing with hot dip galvanized steel wire and monofilament, the best electro-galvanized thermal diffusion process was optimized. The results show that with increasing thermal diffusion temperature, the Zn-Fe alloy phase in the electro-galvanized steel wire coating increased, and the Fe-rich phase increased, while the Zn-rich phase decreased. When the temperature was above 520℃, the Fe3Zn10 brittle phase was formed, and cracks appeared in the coating. Compared with the hot dip galvanized monofilament, the electro-galvanized monofilament treated by thermal diffusion at 480℃ had higher tensile strength, less coating loss, and similar fatigue life, which met the requirements for the use of monofilament for elevator traction belt wire ropes.
  • Material Properties & Application
  • CHEN Yanfei, ZHANG Jinxiang, LENG Xiang, XU Yuyou, WANG Guangxin, WANG Yuxiang
    Materials For Mechanical Engineering. 2022, 46(3): 38-44. https://doi.org/10.11973/jxgccl202203007
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    Using pure magnesium ingot and Mg-30Ce master alloy as raw materials, Mg-Ce alloys with Ce mass fractions of 0.1%, 0.5% and 1% were prepared by melting, and were solution treated at 420℃ for 8 h. The effect of solution treatment on the microstructure and corrosion resistance of alloys with different Ce contents was investigated. The results show that a large amount of Mg-Ce rare earth phase was precipitated at the grain boundaries and in the grains of as-cast Mg-Ce alloys with different Ce contents, and the amount of rare earth phase increased with increasing Ce content. After solution treatment, the rare earth phase was mostly dissolved in the magnesium matrix. The corrosion form of as-cast alloys with different Ce contents was pitting corrosion. The rare earth phase and the magnesium matrix formed a galvanic cell, and the magnesium matrix was protected as a cathode, so the alloy had good corrosion resistance. After solution treatment, the Ce element was dissolved in the magnesium matrix to enlarge the corrosion area, compared with the as-cast state, the self-corrosion current of the alloy increased significantly, the corrosion resistance decreased, and the corrosion form changed to surface corrosion. The higher the Ce content, the worse the corrosion resistance of the alloy.
  • LI Zhenhao, ZHAO Pifeng, MIAO Xin, YAO Shangjun, CHEN Sijie
    Materials For Mechanical Engineering. 2022, 46(3): 45-50. https://doi.org/10.11973/jxgccl202203008
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    Transient liquid phase diffusion bonding of 5A06 aluminum alloy was carried out by using Al-Cu-Si-Ni amorphous foil as the interlayer in argon protection atmosphere with banding time of 10 min and bonding pressure of 2.5 MPa. The influences of bonding temperature (550-590℃) on the microstructure and performance of joints were studied. The results show that the increase of bonding temperature could promote the diffusion of interlayer melting point depressant elements(Cu,Si and Ni), and reduce the formation of brittle phase in weld microstructure, and thus improve the tensile strength of the joint; but the tensile strength of the joint decreased when the bonding temperature was 590℃. The optimum bonding temperature was 580℃ under test conditions; at this point, the diffusion of melting point depressant elements between the interlayer and the base metal was sufficient, and the joint interface was fuzzy, indicating the joint quality was good; the weld center had the smallest hardness of 76.5 HV and the largest tensile strength of 239 MPa, and the fracture mode was ductile fracture.
  • SONG Ailing, CAO Tieshan, CHENG Congqian, ZHAO Jie
    Materials For Mechanical Engineering. 2022, 46(3): 51-56. https://doi.org/10.11973/jxgccl202203009
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    HR3C steels with three grain morphologies (fine, coarse and elongated) were prepared by hot forging and solution treatment. The microstructure, precipitation morphology, hardness and impact toughness were investigated after aging at 700℃ for 500-2 000 h, and the effect of grain morphology on aging brittleness was discussed. The results show that HR3C steel with coarse grains had uniform grain size distribution, and M23C6 carbides continuously precipitated along grain boundaries. The steel had low hardness and impact toughness, and exhibited brittle fracture after aging. HR3C steel with fine grains had uniform grain size distribution, M23C6 carbides were distributed in chains at grain boundaries. The steel had higher hardness and impact toughness, and exhibited a mixed fracture of brittleness and ductility after aging. HR3C steel with elongated grains had an uneven grain size distribution, and M23C6 carbides had a discontinuous distribution grain boundaries. The steel had high hardness and impact toughness, and exhibited ductile fracture after aging.
  • ZHOU Rui, HAN Wenjing, SHI Weiwei, LI Guosheng, LIU Shuai
    Materials For Mechanical Engineering. 2022, 46(3): 57-62. https://doi.org/10.11973/jxgccl202203010
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    Carbon ceramic composite for aircraft brake block with density of 2.0-2.2 g·cm-3 was prepared on the basis of carbon carbon body by liquid phase siliconizing method. The phase composition, microstructure and mechanical properties of the material were studied. By simulating different braking conditions of aircraft, the dry and wet friction and wear performance of the material friction pair under 1.4 MJ load was studied by a large sample test bench. The results show that the material was composed of carbon phase, β-SiC phase and silicon phase, and SiC phase mainly distributed between carben fiber bundles and the mesh layer composed of chopped carbon fibers. The material had vertical and parallel bending strength of 132.7, 135.5 MPa, respectively and interlaminar shear strength of 12.2 MPa. Under the braking pressure of 0.2-0.5 MPa and the braking speed of 5-27 m·s-1, with increasing the braking speed, the dry dynamic friction coefficient of the material increased first and then decreased in the range of 0.30-0.65, and was negatively correlated with the braking pressure. Under the braking pressure of 0.5 MPa, when the braking speed increased from 25 m·s-1 to 27 m·s-1, the attenuation rate of wet dynamic friction coefficient was less than 10%. Under the braking pressure of 0.55 MPa and the braking speed of 25 m·s-1, the average linear wear rate of each surface per time was 0.001 2-0.001 3 mm, and the overall wear rate was small and relatively stable.
  • ZHANG Kun, LUO Wenfeng, GUO Xiaotong, HUANG Kai, ZHU Gang
    Materials For Mechanical Engineering. 2022, 46(3): 63-67. https://doi.org/10.11973/jxgccl202203011
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    45 steel rods in forged and normalized state with a diameter of 8 mm for sealing plug were quenched at 750-880℃ for 15 min and high temperature tempered at 550℃ for 30 min. The microstructure, fracture morphology and hardness of the specimens at different quenching temperatures were studied. The effect of quenching temperature on quenching cracking was analyzed and the heat treatment process was optimized. The results show that the specimens did not crack after quenching at 750℃ and 780℃, and cracked after quenching at 800-880℃. With increasing quenching temperature, the ferrite content in microstructure decreased, the grain size increased, and the hardness first increased and then decreased. When the quenching temperature ranged from 800℃ to 830℃, the cause of quenching cracking was that the cooling rate of undercooled austenite in the martensite transformation phase region was too large, and the structural stress was concentrated in the outer layer of the specimen, which led to the propagation of crack in a mixed mode of intergranular and transgranular. When the quenching temperature ranged from 850℃ to 880℃, the grain boundary was weakened due to the higher quenching temperature, and cracks propagated along grain boundaries under the combined action of the structural stress and the thermal stress. The best tempered sorbite structure and relatively high hardness of 45 steel could be obtained and the quenching cracking could be avoided by setting a slow cooling process of 3-5 s at room temperature before quenching at 830℃ and then tempering.
  • Physical Simulation & Numerical Simulation
  • YU Xinping, PAN Guangyong, HUANG Qinghua, PAN Qiaoyu
    Materials For Mechanical Engineering. 2022, 46(3): 68-74,82. https://doi.org/10.11973/jxgccl202203012
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    The compression deformation test of as-rolled TC21 alloy in α+β two-phase region was carried out by using Gleeble-3500 thermal simulation test machine. The microstructure and flow stress curves of the alloys at different hot deformation temperatures (870-960℃) and strain rates (0.001-1 s-1) were studied. The flow stress constitutive equation and dynamic recrystallization dislocation density model were established, and the microstructure was simulated and verified. The results show that the softening mechanism of flow stress curve of the alloy was mainly dynamic recrystallization. When the strain rate was constant, the content of α phase in the deformed microstructure decreased continuously with increasing deformation temperature, and the size of α phase increased first and then decreased. When the deformation temperature was 870℃ and 900℃, the size of α phase decreased first and then increased with increasing strain rate. When the deformation temperature reached 930℃, which was close to the transformation point, the α phase content decreased sharply, and the β phase grain was dynamically recrystallized, and the grain size was refined. The established stress calculation model was used to predict the peak stress, and the results were relatively accurate with an average relative error of 6.274%. The simulation results of the dynamic recrystallization microstructure based on the flow stress constitutive equation and the dislocation density model were basically consistent with the microstructure obtained by the experiment, and the calculation model was relatively accurate.
  • XING Qingyuan, HE Weiwei, WANG Hailong, YANG Shoujie
    Materials For Mechanical Engineering. 2022, 46(3): 75-82. https://doi.org/10.11973/jxgccl202203013
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    Al-8.8Zn-1.4Mg-0.5Cu-0.1Sc-0.1Er-0.1Zr alloy was subjected to isothermal compression tests on Gleeble 3800 thermal simulation testing machine under conditions of deformation temperature of 380-440℃, strain rate of 0.01-10 s-1 and deformation amount of 45%, 60%. The hot deformation behavior of the alloy was studied, and the deformation constitutive equation and hot processing map based on dynamic material model were established. The best range of hot processing parameters was confirmed, and the microstructure of characteristic zone was observed. The results show that test alloy showed characteristics of isothermal rheological, sensitivity of positive strain rate and negative temperature. The best range of hot processing parameters within test range was deformation temperature of 425-440℃ and strain rate of 0.01-0.02 s-1. The instability zone of the alloy mainly appeared in the condition of large strain, low deformation temperature and large deformation amount. The dislocation pile-up and adiabatic shear band in the microstructure were main reasons for the instability of test alloy.
  • LI Qin, TANG Chongyao, CHANG Weichun, GUO Xu, LI Dejie, XU Zhaodong
    Materials For Mechanical Engineering. 2022, 46(3): 83-88,94. https://doi.org/10.11973/jxgccl202203014
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    Based on the heat source and constitutive equation of the metal active gas arc girth weld between the X80 steel large-size pipe and the B-type sleeve, the finite element model of the welded joint was established, and the residual stress distribution of the welded joint under three welding sequences of simultaneous welding of both left and right ends, the alternate welding of both left and right ends, and welding successively of both left and right ends were simulated, and the accuracy of the simulation results was verified by the blind hole method. The influence of welding sequence on the welding residual stress was discussed. The results show that the maximum residual stress in the welded joints was located within 1.8-3 mm from the outer wall to the capping bead, and the residual stress distribution at the left and right ends of the pipe and sleeve was similar under different welding sequences. The peak residual stress of the pipe and sleeve under the welding sequence of simultaneous welding of both left and right ends was the largest, which were located near the welding point of the outer wall. The relative error between finite element simulation results and test results was less than 9.15%, which verified the accuracy of the simulation results. The welding sequence of welding successively of both left and right ends had the smallest influence on the maximum welding residual stress.
  • Failure Analysis
  • LIU Ming, BAI Jia, WANG Lu, FANG Lulu, DING Qiaofeng
    Materials For Mechanical Engineering. 2022, 46(3): 89-94. https://doi.org/10.11973/jxgccl202203015
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    A spring pull rod of constant spring support with three connecting rods of a thermal power unit was broken. The fracture cause of spring pull rod was analyzed by means of macro and micro morphology observation, chemical composition analysis, microstructure observation, mechanical property testing and force simulation. The results show that the material of fractured spring pull rod was non-quenched and tempered 45 steel with poor fatigue performance. Stress concentration at the root of the first thread was caused by the insufficient thread processing length and surface processing defects of the spring pull rod, which formed the crack source. During the operation of constant spring support with three connecting rods, the internal spring pull rod was deflected and subjected to additional bending moment. Under the joint action of axial tension, bending load, and additional alternating stress produced by pipe vibration, low stress high cycle fatigue fracture of the spring pull rod occurred.