20 June 2021, Volume 45 Issue 6
    

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  • TIAN Wenqi, YANG Dongye, LI Jiuxiao
    Materials For Mechanical Engineering. 2021, 45(6): 1-7. https://doi.org/10.11973/jxgccl202106001
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    Selective laser melting and electron beam selective melting additive manufacturing are ideal advanced high energy beam additive manufacturing techniques. The selective laser melted and energy beam selective melted Ti-Al alloy had a fine microstructure, and better mechanical properties than the cast alloy. The alloy can obtain good high-temperature creep resistance and ductility by reasonable heat treatments after the forming. The high energy beam additive manufacturing technique can solve the traditional forming problem of Ti-Al alloy component. The research progress on the preparation of Ti-Al prealloyed powder, the process and application of selective laser melting and electron beam selective melting, and the microstructure and properties of Ti-Al alloy are reviewed. The future research direction of Ti-Al alloy prepared by high-energy beam additive manufacturing is prospected.
  • YU Shuifeng, YANG Yuming
    Materials For Mechanical Engineering. 2021, 45(6): 8-13,25. https://doi.org/10.11973/jxgccl202106002
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    A Ni-P-Al2O3-PTFE (polytetrafluoroethylene) composite plating was prepared by electroless plating method with different content of Al2O3 in the composite plating solution. The effects of mass concentration (0-3.0 g·L-1) of Al2O3 in the composite plating solution on the microstructure, hardness and wear resistance of the composite plating were studied. The results show that with increasing doping content of Al2O3 in the composite plating solution, the content of Al2O3 in the electroless plating Ni-P-Al2O3-PTFE composite plating increased first and then decreased, the crystallinity of the Ni-P matrix increased first and then decreased, the hardness increased first and then decreased, and the wear mass loss decreased first and then increased. When the mass concentration of Al2O3 was 2.0 g·L-1, the crystallinity of the Ni-P matrix was good, the Ni-P-Al2O3-PTFE plating and Ni-P transition layer were bonded well, the content of Al2O3 in the composite plating was the highest, the PTFE and Al2O3 particles were uniformly dispersed in the Ni-P matrix, and the composite plating had the highest hardness of 7.6 GPa, and the smallest wear mass loss, indicating the composite plating had excellent wear resistance.
  • DAI Wei, ZHU Xiang, KANG Wenjie, JIN Shugang
    Materials For Mechanical Engineering. 2021, 45(6): 14-19,56. https://doi.org/10.11973/jxgccl202106003
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    Inconel600 alloy tube treated by solution and cold rolling cracked longitudinally after repeated cold drawing, and the cracking reason for Inconel600 alloy tube was studied from the aspects of microstructure, non-metallic inclusion, cracking morphology, mechanical properties, processing properties, and solution treatment. The results show that the content of nitrogen was high in the Inconel600 alloy tube, and there were a lot of oxide and nitride formed during smelting process. During cold rolling before cold drawing, the oxide and nitride were chain-like distributed along the rolling direction, and large chain inclusions destroyed the uniform continuity of matrix. During repeated drawing process, stresses were concentrated on the inclusions, leading to microcrack initiation here and propagation, and eventually the alloy tube cracked longitudinally.
  • GAO Bang, LIU Ying, HE Zhiyong, YU Shengwang, MENG Jie, MA Yong, ZHOU Bing, WU Yanxia
    Materials For Mechanical Engineering. 2021, 45(6): 20-25. https://doi.org/10.11973/jxgccl202106004
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    MoO2/C nanofiber composite films were prepared by electrospinning with mass ratios of ammonium molybdate (AMT) to pure polyvinyl alcohol (PVA) of 1:9,2:8,3:7;4:6, repectively. The microstructure of the film and electrochemical property of the corresponding electrode were studied. The results show that with increasing AMT to PVA mass ratio, the fiber size of MoO2/C nanofiber composite film decreased, the fiber distribution became uniform, and the filament forming effect was improved. Moreover, the specific capacitance of the corresponding electrode increased, and the cycle performance was enhanced. When the AMT to PVA mass ratio was 4∶6, the filament forming effect of the film was the best, and the corresponding electrode had good structural stability in the charge and discharge cyclic process. Meanwhile its cycle retention rate, charge specific capacity, discharge specific capacity and charge-discharge efficiency all increased after 5 000 charge-discharge cycles, and the cycle performance was excellent.
  • WANG Ze, WANG Peiqing, WANG Guoqing
    Materials For Mechanical Engineering. 2021, 45(6): 26-30. https://doi.org/10.11973/jxgccl202106005
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    Castor oil was modified by grafting aggregation induced emission fluorescent monomer (TPE-COOH) and then was used to prepare water-based fluorescent silicate polymer coatings. The effects of content of TPE-COOH and modified castor oil on the surface morphology, mechanical properties, fluorescence property and antifouling property of the coatings were studied. The results show that the surface of water-based fluorescent silicate polymer coating was smooth and uniform. With increasing content of TPE-COOH modified castor oil, the adhesion and the maximum fluorescence intensity of the coating increased, and the hardness decreased. The content of the TPE-COOH had no significant effect on the mechanical properties of the coating. Compared with those of the unmodified silicate polymer coating, the adhesion and antifouling effect of the water-based fluorescent silicate polymer coating were improved. When the mass ratio between castor oil modified by TPE-COOH, silicate slurry and curing agent was 1:10:5.5, the coating had good comprehensive mechanical properties and antifouling properties.
  • TANG Jingyi, CAI Yixiong, SHAO Yanqun, ZHANG Yanbin
    Materials For Mechanical Engineering. 2021, 45(6): 31-38. https://doi.org/10.11973/jxgccl202106006
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    The Ti/SnO2-NiO-RuO2 electrodes with different doping amounts (0, 9.1%, 16.7%, 23.1%, 28.6%, mole fraction) of RuO2 were prepared by thermal decomposition method. The effect of doping amount of RuO2 on the electrocatalytic degradation performance of the Ti/SnO2-NiO-RuO2 electrodes was studied. The results show that doping RuO2 increased the concentration of adsorbed oxygen, the number of active sites and the kinds of valence states of ions on the surface of Ti/SnO2-NiO-RuO2 electrode. Moreover, the specific surface area and voltammetric charge density of the electrode were improved, the electrocatalytic degradation was promoted, and the strengthening life of the electrode was prolonged. The Ti/SnO2-NiO-RuO2 electrode had the fastest electrocatalytic degradation speed for methyl orange when the doping amount of RuO2 was 23.1%, and the degradation rate was the largest, reaching 87% after degradation for 3 h, which was 30% higher than that of the electrode undoped RuO2; the electrode had a good electrocatalytic effect.
  • JING Fengting, CHEN Rongchun, ZHANG Yinghui, WANG Hang, SONG Chunmei, WANG Zhigang
    Materials For Mechanical Engineering. 2021, 45(6): 39-45. https://doi.org/10.11973/jxgccl202106007
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    The microstructure and hardness of B10 white copper alloy with different Y content (0,0.003 9wt%,0.021wt%,0.053wt%,0.15wt%) after annealing at different temperatures (200-800 ℃) were studied, and the effect of Y on recrystallization behavior was analyzed. The results show that B10 alloy was in the early stage of recrystallization in annealing at 350-650 ℃, and was in the later stage of recrystallization in annealing at 650-800 ℃. In the early stage of recrystallization, Y mainly affected the nucleation of recrystallization. When the content of Y was less than 0.003 9wt%, Y was not conducive to recrystallization nucleation. When the content of Y was more than 0.003 9wt%, Y promoted recrystallization nucleation obviously. At the same temperature, the hardness of the alloy was the highest when the content of Y was 0.003 9wt%, and was the lowest when the content of Y was 0.150 0wt%. In the later stage of recrystallization, Y could suppress the growth of recrystallization grains. The higher content of Y, the more the number of the composite inclusions, the larger the inclusion size, the higher the pinning force acting on grain boundaries, and the finer the grains. At this stage, the hardness decreased sharply with increasing annealing temperature. The hardness of the alloy with 0.15wt% Y was the highest after annealing at 800 ℃, while the hardness of other alloys was basically the same.
  • SONG Zibo, WANG Zhichun, WANG Jianguo, PENG Bo, ZHANG Chuanzheng
    Materials For Mechanical Engineering. 2021, 45(6): 46-51. https://doi.org/10.11973/jxgccl202106008
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    The atmospheric corrosion test was conducted on Q235 steel in northern Hebei region (Tangshan, Qinhuangdao, Langfang, Chengde, and Zhangjiakou city) for 1 a, and the corrosion rates of Q235 steel in different cities were compared. The effects of Cl- deposition rate, SO2 content and humidity in the atmospheric environment at center positions of five cities (Angezhuang, Tianma, Bazhou, Longcheng, Wanquan) on the corrosion rate of Q235 steel were studied, and the morphology of the corrosion products was observed. The results show that the corrosion rate of Q235 steel decreased gradually from southeast to northwest. The effect of Cl- on corrosion rate was relatively small because of the relatively low deposition rate. The influence of SO2 content on corrosion rate was greater than that of Cl-, and the influence of air relative humidity was the largest. The corrosion rate of Q235 steel at Angezhuang station was relatively fast, and the surface corrosion products were mainly lamellar γ-FeOOH, which had relatively small protective effect on the matrix. The corrosion rates at Bazhou and Tianma stations were the second, and the corrosion products were mainly cluster-shaped α-FeOOH. The corrosion rates at Wanquan and Longcheng stations were relatively slow, and the surface corrosion products were mainly cotton-flock-like α-FeOOH, which had relatively large protective effect on the matrix.
  • YANG Pengfei, FAN Junling, NING Ning, SHI Junwei
    Materials For Mechanical Engineering. 2021, 45(6): 52-56. https://doi.org/10.11973/jxgccl202106009
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    The effect of porosity on compressive strength of IMA carbon fiber reinforced M21 epoxy resin composite plate was studied by compression test, and a nonlinear relationship model between porosity and compressive strength was established. The results show that when the porosity no more than 1.87%, the compressive strength of the composite plate did not change obviously compared with that of the porosity of 0, and the effect of the porosity on the compressive strength was relatively small. When the porosity grater than 1.87%, the compressive strength of the composite plate was obviously lower than that of the porosity of 0, and the effect of the porosity on the compressive strength was relatively large. The compressive strength of the composite plate was predicted by the established nonlinear relationship model between porosity and compressive strength, and the prediction result was more accurate than that of Gürdal index model.
  • XUE Houqing, SUN Changle, JIANG Xinqi, HU Hao, YANG Jichen
    Materials For Mechanical Engineering. 2021, 45(6): 57-61,69. https://doi.org/10.11973/jxgccl202106010
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    Considering the effects of coating, and the effects of tensile time, tensile rate, viscoelastic stress and reaction force on initial stress, the improved hyperelastic constitutive and viscoelastic constitutive model of thermoplastic polyurethane composite fabric and a single fiber bundle were established by tensile test. The stress-strain and stress relaxation curves during the tensile process were predicted and compared with the test results. The results show that the established hyperelastic constitive model could accurately predict the stress-strain curve of the fabric and the single fiber bundle, and the realtive errors were less than 3.5%. The viscoelastic constitutive model could accurately predict the stress relaxation curve of the fabric, and the relative error was less than 3.21%.
  • SUN Shuqi, WANG Runzi, YUAN Guangjian, CHEN Hao, GAO Jianbao, PENG Wei, ZHANG Xiancheng, ZHANG Lijun
    Materials For Mechanical Engineering. 2021, 45(6): 62-69. https://doi.org/10.11973/jxgccl202106011
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    The grain growth during the annealing process of pure copper with homogeneous and heterogeneous structure (gradient structure and bimodal structure) were simulated by the phase field model and the ideal grain growth model. The results show that the change of grain boundary energy barrier had little effect on the growth rate of grain with homogeneous structure. When the annealing time was longer than 600 s, the growth rate of homogeneous structural grains had a larger step change. For heterostructural grains, the greater the grain boundary energy barrier, the slower the grain growth. In the gradient structure, the growth rate of small grains was the fastest, followed by that of medium grains, and that of large grains was the slowest. The larger the grain size, the smaller the influence of the grain boundary energy barrier on the growth rate. In the bimodal structure, the grain boundary energy barrier had greater influence on the growth rate of coarse grains than the fine grains. The growth rate of fine grains significantly decreased and of coarse grains increased after increasing number of coarse grains.
  • LIU Pengpeng, YE You, WEI Yifan
    Materials For Mechanical Engineering. 2021, 45(6): 70-73,78. https://doi.org/10.11973/jxgccl202106012
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    The automobile reinforcement plate produced by a company cracked before final assembly, whose material was 22MnB5 hot stamping steel with Al-Si coating. The failure reason was analyzed by fracture morphology and microstructure observation, and chemical composition and hardness tests. The results show that the fracture mode of the failed reinforcement plate was a mixture fracture of ductile and brittle. The corner radius was relatively small during laser trimming blanking, leading to the crack initiation at the edge of trimming. The cracks propagated rapidly along the bending deformation region without laser trimming under the impact load during transport. By increasing radius at the corner and all-round laser trimming of the reinforcement plate after stamping, the indentation on the coating of the reinforcement plate became shallow before final assembly, and no cracking occurred.
  • LI Lifeng, CHEN Yue, REN Guoqi, ZHU Lixia, WU Gang, LUO Jinheng
    Materials For Mechanical Engineering. 2021, 45(6): 74-78. https://doi.org/10.11973/jxgccl202106013
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    Cracking occurred on the branch pipe side of an equal diameter seamless tee during the process of pressure testing and putting into production. The cracking reason was analyzed by morphology and microstructure observation, nondestructive testing, and chemical composition and mechanical property tests. The results show that the cracking location of the failed tee was on the girth weld of the branch pipe, and the girth weld was produced in the manufacturing stage of the tee, which did not meet the production quality requirements of the equal diameter seamless tee. The main reason for cracking was that there were serious incomplete penetration defects in the girth welds. With increasing test pressure, cracks were initiated at the incomplete penetration defects and expanded until penetrating the remaining wall thickness.
  • ZHU Mingjun, ZHANG Ganghua, LI Shasha, ZENG Tao
    Materials For Mechanical Engineering. 2021, 45(6): 79-84,93. https://doi.org/10.11973/jxgccl202106014
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    Ferroelectric materials have unique photovoltaic properties due to their polarized electric field, and are widely used in many fields, especially in photovoltaic power generation. The generation mechanism of internal electric field (photovoltaic mechanism) in ferroelectric materials, and the effects of electric field regulation mechanism on photovoltaic properties of ferroelectric materials are reviewed from aspects of the preparation of narrow band gap ferroelectric materials, enhancing visible light absorption by self-doping of oxygen deficiency constructing composite heterojunction, preparing multipole axial molecular ferroelectrics, and regulating the domain orientation and distribution in ferroelectric materials by external polarization field. The research direction of improving photovoltaic performance by regulating internal electric field is pointed out.
  • HUANG Jian, ZHANG Xuewu, JIANG Chunyan, ZENG Tao, ZHUANG Xuning
    Materials For Mechanical Engineering. 2021, 45(6): 85-88,98. https://doi.org/10.11973/jxgccl202106015
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    Pb<sub>(1-2x/3)Lax(Ti0.99Mn0.01)O3 piezoelectric ceramics were prepared by solid-phase sintering method. The effects of lanthanum doping amount (x=0.005,0.045,0.075,0.150,mole fraction) on the lattice constant, piezoelectric anisotropy, dielectric constant, dielectric loss, Curie temperature and mechanical quality factor of the piezoelectric ceramics were studied. The results show that with increasing lanthanum doping amount, the axial ratio of the lattice (c/a) of the piezoelectric ceramics decreased, the anisotropy and the tetragonal structure was weakened, the dielectric loss was reduced, and the mechanical quality factor increased. The La doping was helpful for the improvement of the piezoelectric property, but resulted in the decrease of the piezoelectric anisotropy and the Curie temperature and the increase of the dielectric constant.
  • YAO Xiaocheng, JIANG Chunyan, ZHAO Cheng, ZENG Tao
    Materials For Mechanical Engineering. 2021, 45(6): 89-93. https://doi.org/10.11973/jxgccl202106016
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    The piezoelectric actuator was designed and developed on the basis of the structural characteristics of the piezoelectric stack. The optimal preloading force of the piezoelectric actuator was determined. The piezoelectric actuator with the preloading force was connected with inertia mass block to form an inertial piezoelectric actuator. The vibration reduction effect of the inertial piezoelectric actuator was studied. The results show that the optimal preloading force of the piezoelectric actuator was 225 N, and the corresponding maximum output displacement was 10.35 μm. The vibration reduction test device with the maximum output displacement of the piezoelectric actuator of 10.35 μm and the mass of the inertial mass block of 130 g, the inertial piezoelectric actuator had good vibration reduction effect when the vibration frequency were 50, 75, 100 Hz.
  • HUANG Jian, ZHANG Xuewu, ZHAO Cheng, ZENG Tao, ZHUANG Xuning
    Materials For Mechanical Engineering. 2021, 45(6): 94-98. https://doi.org/10.11973/jxgccl202106017
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    Lead titanate series ceramics are important functional materials and are widely used in piezoelectric field. The ceramics are difficult to sinter and polarize, and the piezoelectric property is relatively low. The sintering and piezoelectric properties are research focus at present. The research status of modifying lead titanate series ceramics by element doping and component addition to improve the sintering property and piezoelectric property, and the application of modified ceramics are reviewed. The future research directions are pointed out, including optimization of sintering process, element composite doping and composition design of quasi-homotype phase boundary.
  • ZHAO Xu, ZHANG Hao, ZENG Tao, BAI Jianfeng
    Materials For Mechanical Engineering. 2021, 45(6): 99-102. https://doi.org/10.11973/jxgccl202106018
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    The effects of volume fraction of piezoelectric phase, and elastic modulus and Poisson's ratio of polymer on the piezoelectric properties of 1-3 type piezoelectric ceramic composite were simulated by finite element software, and the simulation was verified by experiments. The results show that the electromechanical coupling coefficient of the composite was relatively high and changed little when the volume fraction of the piezoelectric phase was 30%-85%. With increasing elastic modulus and Poisson's ratio of polymer, the series connection resonance frequency of the composite increased, and the electromechanical coupling coefficient decreased. The finite element model could accurately simulate the series connection resonance frequency and electromechanical coupling coefficient of the relatively hard polymer filled composites, and the relative error was less than 5%. The model was not suitable for the simulation of the electromechanical coupling coefficient of the relatively soft polymer filled composites.