研究论文

焊后热处理对NiCrMo-3熔敷金属腐蚀行为的影响

  • 程虹蓓 ,
  • 曹睿 ,
  • 杨飞 ,
  • 徐晓龙 ,
  • 贾兴旺 ,
  • 蒋勇
展开
  • 1. 兰州理工大学, 省部共建有色金属先进加工与再利用国家重点实验室, 兰州, 730050;
    2. 四川大西洋焊接材料股份有限公司, 自贡, 643000
程虹蓓,硕士;主要研究方向为高温合金焊接性、强韧性、腐蚀、损伤及断裂行为;Email:chenghbmail@163.com.

收稿日期: 2022-09-05

  网络出版日期: 2024-01-16

基金资助

国家自然科学基金资助项目(52175325,51961024,52071170);甘肃省教育厅“双一流”科研重点项目(GSSYLXM-03);甘肃省科技重大专项资助项目(ZZZD6GA008).

Effect of post welding heat treatment on corrosion behavior of NiCrMo-3 deposited metal

  • CHENG Hongbei ,
  • CAO Rui ,
  • YANG Fei ,
  • XU Xiaolong ,
  • JIA Xingwang ,
  • JIANG Yong
Expand
  • 1. State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou, 730050, China;
    2. Atlantic Welding Material Co., Ltd., Zigong, 643000, China

Received date: 2022-09-05

  Online published: 2024-01-16

摘要

以NiCrMo-3合金熔敷金属为研究对象,通过扫描电子显微镜、透射电子显微镜、X射线衍射仪等研究了原始焊态与690 ℃保温8 h热处理态熔敷金属的耐腐蚀性能差异.结果表明,与焊态试样相比,热处理试样具有良好的耐晶间腐蚀性能,在HNO3溶液中浸泡不同的时间发生了点蚀和晶间腐蚀;热处理态金属除了点蚀与晶间腐蚀还发生了部分枝晶间腐蚀行为.热处理后的试样由于NbC,Laves相数量及尺寸的增加导致腐蚀敏感性升高.析出相NbC,Laves相与基体的电位差导致在腐蚀介质作用下发生点蚀.晶界析出物导致Ni,Cr元素含量的降低,从而增加了熔敷金属晶间腐蚀敏感性.热处理后由于元素再分配导致枝晶间Nb,Mo等元素的富集和Ni,Cr等元素的贫化,引起枝晶间腐蚀.

本文引用格式

程虹蓓 , 曹睿 , 杨飞 , 徐晓龙 , 贾兴旺 , 蒋勇 . 焊后热处理对NiCrMo-3熔敷金属腐蚀行为的影响[J]. 焊接学报, 2023 , 44(7) : 32 -39 . DOI: 10.12073/j.hjxb.20220905001

Abstract

In this paper, the difference of corrosion resistance for NiCrMo-3 deposited metal with as-welded and as-PWHT (post welding heat treatment) at 690 ℃ for 8 h was investigated by scanning electron microscope, transmission electron microscopy and other characterization methods. The results show that the as-welded specimens have better intergranular corrosion resistance than that of as-PWHT specimens. Pitting corrosion and intergranular corrosion occur when the specimens were immersed in HNO3 solution for different times. In addition to pitting corrosion and intergranular corrosion, partial inter-dendrite corrosion occurs in as-PWHT deposited metal. The increase of the number and size of NbC and Laves phase leads to the increase of corrosion sensitivity of the specimens after heat treatment. The potential difference between precipitated phase NbC, Laves phase and matrix leads to pitting corrosion under the action of corrosive medium. The contents of Ni and Cr elements decrease due to grain boundary precipitates, which increased the intergranular corrosion sensitivity of deposited metal. After heat treatment, the elements redistribution leads to the enrichment of Nb, Mo elements and depletion of Ni, Cr elements, resulting in inter-dendrite corrosion.

参考文献

[1] Sims C T, Stoloff N S, Hagel W C. Superalloys II[M]. New York: Wiley, 1987.
[2] Xu Tao, Wang Zishun, Shi Yonghua. Investigation of C276 alloy and 316L SS TIG welded joints with ERNiCrMo-4 and ER304 welding wires[J]. China Welding, 2021, 30(4): 9-16.
[3] Wang L, Li H, Liu Q, et al. Effect of sodium chloride on the electrochemical corrosion of Inconel 625 at high temperature and pressure[J]. Journal of Alloys & Compounds, 2017, 703: 523-529.
[4] Abioye T E, Mccartney D G, Clare A T. Laser cladding of Inconel 625 wire for corrosion protection[J]. Journal of Materials Processing Technology, 2014, 217: 232-240.
[5] Fesharaki M N, Shoja-Razavi R, Mansouri H A, et al. Evaluation of the hot corrosion behavior of Inconel625 coatings on the Inconel 738 substrate by laser and TIG cladding techniques[J]. Optics & Laser Technology, 2019, 111: 744-753.
[6] Guo L. Effect of heat treatment temperatures on microstructure and corrosion properties of Inconel 625 weld overlay deposited by PTIG[J]. International Journal of Electrochemical Science, 2016, 97: 5507-5519.
[7] Lemos G V B, Farina A B, Nunes R M, et al. Residual stress characterization in friction stir welds of alloy 625[J]. Journal of Materials Research and Technology, 2019, 8(1): 2528-2537.
[8] Guo L, Xiao F, Wang F, et al. Influence of heat treatments on microstructure, mechanical properties and corrosion resistance of Inconel 625 overlay cladded using PTIG[J]. Materials Research Express, 2020, 7(9): 096517.
[9] Song K H, Nakata K. Effect of precipitation on post-heat-treated Inconel 625 alloy after friction stir welding[J]. Materials & Design, 2010, 31(6): 2942-2947.
[10] Marchese G, Lorusso M, Parizia S, et al. Influence of heat treatments on microstructure evolution and mechanical properties of Inconel 625 processed by laser powder bed fusion[J]. Materials Science & Engineering: A, 2018, 729: 64-75.
[11] Mittra J, Banerjee S, Tewari R, et al. Fracture behavior of Alloy 625 with different precipitate microstructures[J]. Materials Science & Engineering: A, 2013, 574: 86-93.
[12] 郭枭, 徐锴, 霍树斌, 等. 镍基合金焊丝GTAW熔敷金属凝固偏析行为[J]. 焊接学报, 2019, 40(7): 105-108
Guo Xiao, Xu Kai, Huo Shubin, et al. Investigation on the solidification segregation behavior of GTAW nickel alloy deposited metal[J]. Transactions of the China Welding Institution, 2019, 40(7): 105-108
[13] Je S G, Kim D H, Yoo S C, et al. Asymmetric magnetic domain-wall motion by the Dzyaloshinskii-Moriya interaction[J]. Physical Review B, 2013, 88(21): 214401.
[14] Mathew M. D, Parameswaran P, Rao K. Microstructural changes in alloy 625 during high temperature creep[J]. Materials Characterization, 2008, 59(5): 508-513.
[15] Qi H, Azer M, Ritter A. Studies of standard heat treatment effects on microstructure and mechanical properties of laser net shape manufactured Inconel 718[J]. Metallurgical and Materials Transactions A, 2009, 40(10): 2410-2422.
[16] Shimada M, Kokawa H, Wang Z J, et al. Optimization of grain boundary character distribution for intergranular corrosion resistant 304 stainless steel by twin-induced grain boundary engineering[J]. Acta Materialia, 2002, 50(9): 2331-2341.
[17] Kobayashi S, Kobayashi R, Watanabe T. Control of grain boundary connectivity based on fractal analysis for improvement of intergranular corrosion resistance in SUS316L austenitic stainless steel[J]. Acta Materialia, 2016, 102: 397-405.
[18] Xu L, Zhang J, Han Y, et al. Insights into the intergranular corrosion of overlay welded joints of X65-Inconel 625 clad pipe and its relationship to damage penetration[J]. Corrosion Science, 2019, 160: 108169.
[19] Lin P, Palumbo G, Erb U, et al. Influence of grain boundary character distribution on sensitization and intergranular corrosion of alloy 600[J]. Scripta Metallurgica Et Materialia, 1995, 33(9): 1387-1392.
[20] Kjc A, Scy B, Sk C, et al. Microstructural evolution and corrosion behaviour of thermally aged dissimilar metal welds of low-alloy steel and nickel-based alloy[J]. Corrosion Science, 2019, 153: 138-149.
[21] Zhang S, Li H, Jiang Z, et al. Effects of Cr and Mo on precipitation behavior and associated intergranular corrosion susceptibility of super austenitic stainless steel S32654[J]. Materials Characterization, 2019, 152: 141-150.
[22] Xing X, Di X, Wang B. The effect of post-weld heat treatment temperature on the microstructure of Inconel 625 deposited metal[J]. Journal of Alloys & Compounds, 2014, 593: 110-116.
[23] Guo L, Xiao F, Wang F, et al. Effect of post-weld heat treatment temperatures on microstructure, intergranular corrosion resistance, and mechanical properties of 4130 steel with Inconel 625 weld overlay[J]. Journal of Failure Analysis and Prevention, 2021, 21(5): 1775-1783.
[24] Rajani H, Mousavi S, Sani F M. Comparison of corrosion behavior between fusion cladded and explosive cladded Inconel 625/plain carbon steel bimetal plates[J]. Materials & Design, 2013, 43(1): 467-474.
[25] Zhao P. Application of molybdenum in stainless steel[J]. China Molybdenum Industry, 2004, 28(5): 3-10.
[26] Peng Q J, Yamauchi H, Shoji T. Investigation of dendrite-boundary microchemistry in alloy 182 using auger electron spectroscopy analysis[J]. Metallurgical and Materials Transactions A, 2003, 34(9): 1891-1899.
文章导航

/