研究论文

钎焊温度对316L/AuSi/NiTi接头界面组织与力学性能的影响

  • 陈修凯 ,
  • 曹云飞 ,
  • 卞红 ,
  • 宋晓国 ,
  • 姜楠 ,
  • 李明
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  • 1. 哈尔滨工业大学, 先进焊接与连接国家重点实验室, 哈尔滨, 150001;
    2. 哈尔滨工业大学(威海), 山东省特种焊接技术重点实验室, 威海, 264209
陈修凯,硕士;主要研究方向为金属与陶瓷钎焊连接;Email: cxk17852229559@163.com

收稿日期: 2022-08-31

  网络出版日期: 2024-01-16

基金资助

国家自然科学基金青年科学基金资助项目(51905127)

Effect of brazing temperature on interfacial microstructure and mechanical property of 316L/AuSi/NiTi joint

  • CHEN Xiukai ,
  • CAO Yunfei ,
  • BIAN Hong ,
  • SONG Xiaoguo ,
  • JIANG Nan ,
  • LI Ming
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  • 1. State Key Laboratory of advanced welding and joining, Harbin Institute of Technology, Harbin, 150001, China;
    2. Shandong Provincial Key Lab of Special Welding Technology, Harbin Institute of Technology at Weihai, Weihai, 264209, China

Received date: 2022-08-31

  Online published: 2024-01-16

摘要

采用AuSi共晶钎料成功实现了316L不锈钢和NiTi形状记忆合金的连接. 使用扫描电子显微镜和能谱仪等分析测试手段对不同钎焊温度下获得的接头界面组织进行了分析. 结果表明,316L/AuSi/NiTi接头典型界面微观组织为316L/(Fe,Cr)5Si3/Au(s,s) + Ti14Ni49Si37( + Si)/Ni4Si7Ti4 + NiSiTi/NiTi. 随着钎焊温度的升高,316L不锈钢侧(Fe,Cr)5Si3层逐渐形成并变厚,NiTi合金侧的NiSiTi层先增厚后减薄,钎缝中的硅含量逐渐减少. 剪切试验表明,当钎焊温度为600 ℃、保温时间为30 min时,钎焊接头的抗剪强度最高为34 MPa. 接头的断裂路径分析表明,接头沿钎缝中的固溶体发生断裂.

本文引用格式

陈修凯 , 曹云飞 , 卞红 , 宋晓国 , 姜楠 , 李明 . 钎焊温度对316L/AuSi/NiTi接头界面组织与力学性能的影响[J]. 焊接学报, 2023 , 44(7) : 9 -15 . DOI: 10.12073/j.hjxb.20220831001

Abstract

The NiTi shape memory alloy was successfully brazed with 316L stainless steel by AuSi filler metal. The interfacial microstructures of brazed joints at different temperatures were analyzed by scanning electron microscope and energy dispersive spectrometer. The results showed that the typical interfacial microstructure of 316L/AuSi/NiTi joint was 316L/(Fe,Cr)5Si3/Au(s,s)+Ti14Ni49Si37(+Si)/Ni4Si7Ti4+NiSiTi/NiTi. With the rising of temperature, the (Fe,Cr)5Si3 layer on 316L stainless steel side was gradually formed and grew thicker, while the NiSiTi layer on NiTi alloy side was thick at first and then became thinner. Meanwhile, the content of Si in the braze seam decreased gradually. The shear test indicated that the brazed joint at 600 ℃ for 30 min exhibited the highest shear strength of 34 MPa. The path of fracture analysis showed that the joint tended to fracture along the solid solution in the brazing seam.

参考文献

[1] Chen X K, Bian H, Song X G, et al. Effect of glucose contents on electrochemical corrosion behavior of Ti/ZrO2 brazing joint in SBF[J]. ACS Biomater Science & Engineering, 2023, 9(3): 1332-1340.
[2] Jani J M, Leary M, Subic A, et al. A review of shape memory alloy and research, applications and opportunities[J]. Materials & Design, 2014, 56: 1078-1113.
[3] 陈一哲, 杨雨卓, 彭文鹏, 等. 形状记忆合金的应用及其特性研究进展[J]. 功能材料, 2022, 53(5): 5026-5038
Chen Yi Zhe, Yang Yuzhuo, Peng Wenpeng, et al. Research progress on the application and properties of shape memory alloys[J]. Journal of Functional Materials, 2022, 53(5): 5026-5038
[4] Xu T, Wang Z S, Shi Y H. Investigation of C276 alloy and 316L SS TIG welded joints with ERNiCrMo-4 and ER304 welding wires[J]. China Welding, 2021, 30(4): 9-16.
[5] Long W M, Sun H W, Liu D S, et al. Effect of TiC addition on the microstructure and wear resistance of induction brazed nickel-based coating in air[J]. China Welding, 2022, 31(4): 1-6.
[6] 汪洪伟, 谢吉林, 陈玉华, 等. NiTi合金与异种材料焊接技术的研究进展[J]. 金属加工(热加工), 2021(6): 29-36,42
Wang Hongwei, Xie Jilin, Chen Yuhua, et al. Research progress in welding technology between NiTi alloy and dissimilar materials[J]. MW Metal Forming, 2021(6): 29-36,42
[7] Shamsolhodaei A, Oliveira J P, Schell N, et al. Controlling intermetallic compounds formation during laser welding of NiTi to 316L stainless steel[J]. Intermetallics, 2020, 116: 106656-106663.
[8] Niu H, Jiang H C, Zhao M J, et al. Effect of interlayer addition on microstructure and mechanical properties of NiTi/stainless steel joint by electron beam welding[J]. Journal of Materials Science & Technology, 2020, 61(2): 16-24.
[9] Qiu X M, Li M G, Sun D Q, et al. Study on brazing of TiNi shape memory alloy with stainless steels[J]. Journal of Materials Processing Technology, 2006, 176(1-3): 8-12.
[10] Li M G, Sun D Q, Qiu X M, et al. Effects of silver based filler metals on microstructure and properties of laser brazed joints between TiNi shape memory alloy and stainless steel[J]. Science and Technology of Welding and Joining, 2007, 12(2): 183-188.
[11] Zhao X K, Tang J W, Lan L. Vacuum brazing of NiTi alloy by AgCu eutectic filler[J]. Materials Science and Technology, 2009, 25(12): 1495-1497.
[12] Zhao W, Lin P, Lin T, et al. Low temperature joining of NiTi shape memory alloy with Au-Si isothermal solidification[J]. Journal of Manufacturing Processes, 2020, 58: 1034-1038.
[13] Fu W, Xue Y D, Dai J H, et al. Insights into the adsorption and interfacial products improving the wetting of the Ag-Ti/graphite and Cu-Ti/graphite systems: A first-principles calculation[J]. Surfaces and Interfaces, 2023, 38: 102840-102848.
[14] 李明高. TiNi形状记忆合金与不锈钢的连接[D]. 吉林: 吉林大学, 2006.
Li Minggao. Joining of TiNi shape memory alloy and stainless steel[D]. Jinlin: Jilin University, 2006.
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