激光熔覆高铬铁基合金的组织形成机制及对显微硬度的影响

  • 尹燕 ,
  • 潘存良 ,
  • 赵超 ,
  • 张瑞华 ,
  • 屈岳波
展开
  • 1. 兰州理工大学 省部共建有色金属先进加工与再利用国家重点试验室, 兰州 730050;
    2. 中国钢研科技集团有限公司, 北京 100081;
    3. 阳江市五金刀剪产业技术研究院, 阳江 529533
尹燕,女,1973年出生,博士,教授.主要研究方向为高效率焊接及先进的激光加工技术.发表论文30余篇.Email:yinyan@lut.cn

收稿日期: 2018-02-19

  网络出版日期: 2019-08-29

基金资助

增材制造粉末真空气雾化及设备开发(2017003);阳江市五金刀剪产业技术研究院新型研发机构初创期建设补助(611229498090);阳江市高功率激光应用实验室有限公司新型研发机构初创期建设补助(809099997119)

Formation mechanism of microstructure of laser cladding high chromium Fe-based alloy and its effect on microhardness

  • YIN Yan ,
  • PAN Cunliang ,
  • ZHAO Chao ,
  • ZHANG Ruihua ,
  • QU Yuebo
Expand
  • 1. State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China;
    2. China Iron & Steel Research Institute Group, Beijing 100081, China;
    3. Yangjiang Knif-Seissor Hardware Research Institution of Industry Technology, Yangjiang 529533, China

Received date: 2018-02-19

  Online published: 2019-08-29

Supported by

This work is supported by the Science and Technology Program of SGCC(No.5217L017000N).

摘要

采用2 kW光纤碟片激光器在3Cr13不锈钢刀具表面进行同轴送粉激光熔覆高铬铁基合金,以提高刀刃的硬度.通过SEM,EDS,EPMA,XRD分析了熔覆层的显微组织及相组成,采用显微硬度仪进行了硬度测试.结果表明,在凝固的过程中,成分过冷和散热速度的不同,组织大致分为枝晶区、细晶共晶区、粗晶区三个区域,各区域内均分布有(Fe,Cr)7C3,可增加熔覆层的硬度和耐磨性.由于各区域内晶粒的大小不同,使得熔覆层内硬度呈阶梯分布.Ni元素的加入,促进熔覆层中基体奥氏体化,在刀具使用过程中可对高硬度的碳化物起韧性缓冲作用,从而保证了熔覆层的综合力学性能.

本文引用格式

尹燕 , 潘存良 , 赵超 , 张瑞华 , 屈岳波 . 激光熔覆高铬铁基合金的组织形成机制及对显微硬度的影响[J]. 焊接学报, 2019 , 40(7) : 114 -120 . DOI: 10.12073/j.hjxb.2019400192

Abstract

A high chromium iron-base alloy with the coaxial powder laser coating is implemented on the surface of the 3Cr13 stainless steel blade by using 2 kW fibre-optical disc laser to improve the hardness of the blade. SEM, EDS, EPMA and XRD are used to analyze the microstructure of the cladding layer and the microhardness is tested. The results show that the cladding layer is well-formed and metallurgically bonded with the substrate without defects such as cracks, porosity and so on. With the change of the heat dissipation and the constitutional supercooling, microstructure can be roughly divided into three regions:dendritic region, eutectic fine grain region and coarse grain region. The carbides of (Fe,Cr)7C3 is distributed in each region to increase the hardness and abrasion resistance of the cladding layer. As the size of the grain in each region is different, the hardness of the cladding layer is differently distributed. While, the addition of Ni element promotes the austenization of the matrix in the cladding layer. It can play a role in the toughness of the carbides with high hardness during the use of the knife. Thus, the comprehensive mechanical properties of the cladding layer are obtained.

参考文献

[1] 招富刚.广东省阳江市五金刀剪产业技术线路图[M].广州:华南理工大学出版社, 2014.
[2] 王传礼,赵国明. 3Cr13不锈钢循环热处理工艺探讨[J].热处理技术与装备, 2010, 31(1):43-44 Wang Chuanli, Zhao Guoming. Discussion on cyclic heat treatment process of 3Cr13 stainless steel[J]. Heat Treatment Technology and Equipment, 2010, 31(1):43-44
[3] 董世运,马运哲,徐滨士,等.激光熔覆材料研究现状[J].材料导报, 2006, 20(6):5-9 Dong Shiyun, Ma Yunzhe, Xu Binshi, et al. The research development of laser cladding materials[J]. Materials Review, 2006, 20(6):5-9
[4] 李美艳,韩滨,高宁,等.柱塞表面激光熔覆铁基涂层的强韧化机理[J].焊接学报, 2014, 35(2):19-22 Li Meiyan, Han Bin, Gao Ning, et al. Strengthening and toughening mechanism of laser cladding Fe-based coating on plunger surface[J]. Transactions of the China Welding Institution, 2014, 35(2):19-22
[5] 尹燕,栗子林,许广伟,等. 3Cr13碟片激光同轴送粉熔覆层的显微硬度与组织[J].焊接学报, 2016, 37(10):86-87 Yin Yan, Li Zilin, Xu Guangwei, et al. Microhardness and microstructure of laser cladding layer on 3Cr13 kitchen knife by disc laser coaxial powder[J]. Transactions of the China Welding Institution, 2016, 37(10):86-87
[6] 李林起,姚成武,黄坚,等.激光熔覆高硬度铁基涂层枝晶间残余奥氏体相特征[J].中国激光, 2017, 44(3):1-5 Li Linqi, Yao Chengwu, Huang Jian, et al. Characteristics of interdendritic residual austenite in laser cladding of hagh hardness Fe-based coating[J]. Chinese Journal Lasers, 2017, 44(3):1-5
[7] 张文钺.焊接冶金学[M].北京:机械工业出版社, 1999.
[8] 宋建丽,邓琦林,胡德金,等.激光熔覆成形316L不锈钢组织的特征与性能[J].中国激光, 2005, 32(10):1441-1444 Song Jianli,Deng Qilin,Hu Dejin,et al. Microstructure characterization and properties of laser cladding foeming 316L stainless steel[J]. Chinese Journal Lasers, 2005, 32(10):1441-1444
[9] Chia-ming Chang, Chi-Ming Lin, Chih-Chun Hsieh, et al. Micro-structural characteristics of Fe-40wt% Cr-xC hardfacing alloys with[1.0-4.0wt%] carbon content[J]. Journal of Alloys and Compounds, 2009, 487(1-2):83-89.
[10] Gulyaev A P. Carbide transformations in alloys steels[J]. Metal science&Heat Treatment of Metals, 1959, 1(11):54-61.
[11] Wieczerzal K, Bala P, Stepien M, et al. Formation of eutectic carbides in Fe-Cr-Mo-C alloy during non-equilibrium crystallization[J]. Materials Design, 2016, 94:61− 68.
[12] 胡汉起.金属凝固原理[M].北京:机械工业出版社, 2015.
[13] 毛加成,冯爱新,程宝义,等.激光熔覆铁基合金涂层的组织及摩擦磨损性能[J].热加工工艺, 2017, 46(2):139-142 Mao Jiacheng, Feng Aixin, Chen Baoyi et al. Microstructure and friction and wear properties of Fe-based alloy coatings by laser cladding[J]. Hot Working Technology, 2017, 46(2):139-142
文章导航

/